A novel two-dimensional metal–organic framework as a recyclable heterogeneous catalyst for the dehydrogenative oxidation of alcohol and the N-arylation of azole compounds

A novel metal–organic framework (MOF) with two-dimensional (2D) crystal structure was developed using Cu(NO(3))(2)·3H(2)O and 2,2′,5,5′-tetramethoxy-[1,1′-biphenyl]-4,4′-dicarboxylic acid. Further, its structure was characterized using infrared spectroscopy, thermogravimetry, X-ray diffraction, and...

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Autores principales: Liu, Chengxin, Cui, Jin, Wang, Yufang, Zhang, Mingjie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8696073/
https://www.ncbi.nlm.nih.gov/pubmed/35423643
http://dx.doi.org/10.1039/d1ra00248a
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author Liu, Chengxin
Cui, Jin
Wang, Yufang
Zhang, Mingjie
author_facet Liu, Chengxin
Cui, Jin
Wang, Yufang
Zhang, Mingjie
author_sort Liu, Chengxin
collection PubMed
description A novel metal–organic framework (MOF) with two-dimensional (2D) crystal structure was developed using Cu(NO(3))(2)·3H(2)O and 2,2′,5,5′-tetramethoxy-[1,1′-biphenyl]-4,4′-dicarboxylic acid. Further, its structure was characterized using infrared spectroscopy, thermogravimetry, X-ray diffraction, and X-ray crystallography. The activated Cu-MOF was used to catalyze the dehydrogenative oxidation of alcohol and N-arylation of azole compounds. Furthermore, it could be easily recovered and reused.
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spelling pubmed-86960732022-04-13 A novel two-dimensional metal–organic framework as a recyclable heterogeneous catalyst for the dehydrogenative oxidation of alcohol and the N-arylation of azole compounds Liu, Chengxin Cui, Jin Wang, Yufang Zhang, Mingjie RSC Adv Chemistry A novel metal–organic framework (MOF) with two-dimensional (2D) crystal structure was developed using Cu(NO(3))(2)·3H(2)O and 2,2′,5,5′-tetramethoxy-[1,1′-biphenyl]-4,4′-dicarboxylic acid. Further, its structure was characterized using infrared spectroscopy, thermogravimetry, X-ray diffraction, and X-ray crystallography. The activated Cu-MOF was used to catalyze the dehydrogenative oxidation of alcohol and N-arylation of azole compounds. Furthermore, it could be easily recovered and reused. The Royal Society of Chemistry 2021-03-22 /pmc/articles/PMC8696073/ /pubmed/35423643 http://dx.doi.org/10.1039/d1ra00248a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Liu, Chengxin
Cui, Jin
Wang, Yufang
Zhang, Mingjie
A novel two-dimensional metal–organic framework as a recyclable heterogeneous catalyst for the dehydrogenative oxidation of alcohol and the N-arylation of azole compounds
title A novel two-dimensional metal–organic framework as a recyclable heterogeneous catalyst for the dehydrogenative oxidation of alcohol and the N-arylation of azole compounds
title_full A novel two-dimensional metal–organic framework as a recyclable heterogeneous catalyst for the dehydrogenative oxidation of alcohol and the N-arylation of azole compounds
title_fullStr A novel two-dimensional metal–organic framework as a recyclable heterogeneous catalyst for the dehydrogenative oxidation of alcohol and the N-arylation of azole compounds
title_full_unstemmed A novel two-dimensional metal–organic framework as a recyclable heterogeneous catalyst for the dehydrogenative oxidation of alcohol and the N-arylation of azole compounds
title_short A novel two-dimensional metal–organic framework as a recyclable heterogeneous catalyst for the dehydrogenative oxidation of alcohol and the N-arylation of azole compounds
title_sort novel two-dimensional metal–organic framework as a recyclable heterogeneous catalyst for the dehydrogenative oxidation of alcohol and the n-arylation of azole compounds
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8696073/
https://www.ncbi.nlm.nih.gov/pubmed/35423643
http://dx.doi.org/10.1039/d1ra00248a
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