Ligand-free copper-catalyzed C(sp(3))–H imidation of aromatic and aliphatic methyl sulfides with N-fluorobenzenesulfonimide

A novel and efficient process has been developed for copper-catalyzed C(sp(3))–H direct imidation of methyl sulfides with N-fluorobenzenesulfonimide(NFSI). Without using any ligands, various methyl sulfides including aromatic and aliphatic methyl sulfides, can be transformed to the corresponding N-(...

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Autores principales: Wang, Si-Chang, Feng, Ming-Nan, Ji, Yue, Han, Wei-Wei, Ke, Cong-Yu, Zhang, Qun-Zheng, Zhang, Xun-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8696451/
https://www.ncbi.nlm.nih.gov/pubmed/35423744
http://dx.doi.org/10.1039/d1ra00686j
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author Wang, Si-Chang
Feng, Ming-Nan
Ji, Yue
Han, Wei-Wei
Ke, Cong-Yu
Zhang, Qun-Zheng
Zhang, Xun-Li
author_facet Wang, Si-Chang
Feng, Ming-Nan
Ji, Yue
Han, Wei-Wei
Ke, Cong-Yu
Zhang, Qun-Zheng
Zhang, Xun-Li
author_sort Wang, Si-Chang
collection PubMed
description A novel and efficient process has been developed for copper-catalyzed C(sp(3))–H direct imidation of methyl sulfides with N-fluorobenzenesulfonimide(NFSI). Without using any ligands, various methyl sulfides including aromatic and aliphatic methyl sulfides, can be transformed to the corresponding N-((phenylthio)methyl)-benzenesulfonamide derivatives in good to excellent yields.
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spelling pubmed-86964512022-04-13 Ligand-free copper-catalyzed C(sp(3))–H imidation of aromatic and aliphatic methyl sulfides with N-fluorobenzenesulfonimide Wang, Si-Chang Feng, Ming-Nan Ji, Yue Han, Wei-Wei Ke, Cong-Yu Zhang, Qun-Zheng Zhang, Xun-Li RSC Adv Chemistry A novel and efficient process has been developed for copper-catalyzed C(sp(3))–H direct imidation of methyl sulfides with N-fluorobenzenesulfonimide(NFSI). Without using any ligands, various methyl sulfides including aromatic and aliphatic methyl sulfides, can be transformed to the corresponding N-((phenylthio)methyl)-benzenesulfonamide derivatives in good to excellent yields. The Royal Society of Chemistry 2021-03-25 /pmc/articles/PMC8696451/ /pubmed/35423744 http://dx.doi.org/10.1039/d1ra00686j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Wang, Si-Chang
Feng, Ming-Nan
Ji, Yue
Han, Wei-Wei
Ke, Cong-Yu
Zhang, Qun-Zheng
Zhang, Xun-Li
Ligand-free copper-catalyzed C(sp(3))–H imidation of aromatic and aliphatic methyl sulfides with N-fluorobenzenesulfonimide
title Ligand-free copper-catalyzed C(sp(3))–H imidation of aromatic and aliphatic methyl sulfides with N-fluorobenzenesulfonimide
title_full Ligand-free copper-catalyzed C(sp(3))–H imidation of aromatic and aliphatic methyl sulfides with N-fluorobenzenesulfonimide
title_fullStr Ligand-free copper-catalyzed C(sp(3))–H imidation of aromatic and aliphatic methyl sulfides with N-fluorobenzenesulfonimide
title_full_unstemmed Ligand-free copper-catalyzed C(sp(3))–H imidation of aromatic and aliphatic methyl sulfides with N-fluorobenzenesulfonimide
title_short Ligand-free copper-catalyzed C(sp(3))–H imidation of aromatic and aliphatic methyl sulfides with N-fluorobenzenesulfonimide
title_sort ligand-free copper-catalyzed c(sp(3))–h imidation of aromatic and aliphatic methyl sulfides with n-fluorobenzenesulfonimide
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8696451/
https://www.ncbi.nlm.nih.gov/pubmed/35423744
http://dx.doi.org/10.1039/d1ra00686j
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