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DFT calculations bring insight to internal alkyne-to-vinylidene transformations at rhodium PNP- and PONOP-pincer complexes
Density Functional Theory (DFT) has been used to investigate the alkyne-to-vinylidene isomerisation reaction mediated by [Rh(PXNXP)](+) complexes (X = CH(2): 2,6-bis(di-tert-butylphosphinomethyl)pyridine (PNP) and X = O: 2,6-bis(di-tert-butylphosphinito)pyridine (PONOP)) for terminal alkynes HC[trip...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8696595/ https://www.ncbi.nlm.nih.gov/pubmed/35423772 http://dx.doi.org/10.1039/d0ra08764e |