Catalytic enantioselective bromohydroxylation of cinnamyl alcohols

This work describes an effective enantioselective bromohydroxylation of cinnamyl alcohols with (DHQD)(2)PHAL as the catalyst and H(2)O as the nucleophile, providing a variety of corresponding optically active bromohydrins with up to 95% ee.

Detalles Bibliográficos
Autores principales: Li, Jing, Shi, Yian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697332/
https://www.ncbi.nlm.nih.gov/pubmed/35423889
http://dx.doi.org/10.1039/d1ra02297k
Descripción
Sumario:This work describes an effective enantioselective bromohydroxylation of cinnamyl alcohols with (DHQD)(2)PHAL as the catalyst and H(2)O as the nucleophile, providing a variety of corresponding optically active bromohydrins with up to 95% ee.

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