Catalytic enantioselective bromohydroxylation of cinnamyl alcohols

This work describes an effective enantioselective bromohydroxylation of cinnamyl alcohols with (DHQD)(2)PHAL as the catalyst and H(2)O as the nucleophile, providing a variety of corresponding optically active bromohydrins with up to 95% ee.

Detalles Bibliográficos
Autores principales: Li, Jing, Shi, Yian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697332/
https://www.ncbi.nlm.nih.gov/pubmed/35423889
http://dx.doi.org/10.1039/d1ra02297k
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author Li, Jing
Shi, Yian
author_facet Li, Jing
Shi, Yian
author_sort Li, Jing
collection PubMed
description This work describes an effective enantioselective bromohydroxylation of cinnamyl alcohols with (DHQD)(2)PHAL as the catalyst and H(2)O as the nucleophile, providing a variety of corresponding optically active bromohydrins with up to 95% ee.
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spelling pubmed-86973322022-04-13 Catalytic enantioselective bromohydroxylation of cinnamyl alcohols Li, Jing Shi, Yian RSC Adv Chemistry This work describes an effective enantioselective bromohydroxylation of cinnamyl alcohols with (DHQD)(2)PHAL as the catalyst and H(2)O as the nucleophile, providing a variety of corresponding optically active bromohydrins with up to 95% ee. The Royal Society of Chemistry 2021-04-07 /pmc/articles/PMC8697332/ /pubmed/35423889 http://dx.doi.org/10.1039/d1ra02297k Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Li, Jing
Shi, Yian
Catalytic enantioselective bromohydroxylation of cinnamyl alcohols
title Catalytic enantioselective bromohydroxylation of cinnamyl alcohols
title_full Catalytic enantioselective bromohydroxylation of cinnamyl alcohols
title_fullStr Catalytic enantioselective bromohydroxylation of cinnamyl alcohols
title_full_unstemmed Catalytic enantioselective bromohydroxylation of cinnamyl alcohols
title_short Catalytic enantioselective bromohydroxylation of cinnamyl alcohols
title_sort catalytic enantioselective bromohydroxylation of cinnamyl alcohols
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697332/
https://www.ncbi.nlm.nih.gov/pubmed/35423889
http://dx.doi.org/10.1039/d1ra02297k
work_keys_str_mv AT lijing catalyticenantioselectivebromohydroxylationofcinnamylalcohols
AT shiyian catalyticenantioselectivebromohydroxylationofcinnamylalcohols

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