Supporting effects of a N-doped carbon film electrode on an electrodeposited Ni@Ni(OH)(2) core–shell nanocatalyst in accelerating electrocatalytic oxidation of oligosaccharides

The supporting effect of a N-doped carbon film induced superior crystallinity in electrodeposited Ni@Ni(OH)(2) core–shell nanoparticles. This improvement resulted in a much higher regeneration rate of catalytic sites (NiOOH), leading to higher oxidation currents of sugars. Also, the overpotential of...

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Detalles Bibliográficos
Autores principales: Shiba, Shunsuke, Ohta, Saki, Ohtani, Kazuya, Takahashi, Shota, Kato, Dai, Niwa, Osamu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697587/
https://www.ncbi.nlm.nih.gov/pubmed/35423851
http://dx.doi.org/10.1039/d1ra01157j
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author Shiba, Shunsuke
Ohta, Saki
Ohtani, Kazuya
Takahashi, Shota
Kato, Dai
Niwa, Osamu
author_facet Shiba, Shunsuke
Ohta, Saki
Ohtani, Kazuya
Takahashi, Shota
Kato, Dai
Niwa, Osamu
author_sort Shiba, Shunsuke
collection PubMed
description The supporting effect of a N-doped carbon film induced superior crystallinity in electrodeposited Ni@Ni(OH)(2) core–shell nanoparticles. This improvement resulted in a much higher regeneration rate of catalytic sites (NiOOH), leading to higher oxidation currents of sugars. Also, the overpotential of the maltopentaose (G5) oxidation reaction decreased significantly, probably due to the effect of the electrostatic interaction between NPs and G5.
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spelling pubmed-86975872022-04-13 Supporting effects of a N-doped carbon film electrode on an electrodeposited Ni@Ni(OH)(2) core–shell nanocatalyst in accelerating electrocatalytic oxidation of oligosaccharides Shiba, Shunsuke Ohta, Saki Ohtani, Kazuya Takahashi, Shota Kato, Dai Niwa, Osamu RSC Adv Chemistry The supporting effect of a N-doped carbon film induced superior crystallinity in electrodeposited Ni@Ni(OH)(2) core–shell nanoparticles. This improvement resulted in a much higher regeneration rate of catalytic sites (NiOOH), leading to higher oxidation currents of sugars. Also, the overpotential of the maltopentaose (G5) oxidation reaction decreased significantly, probably due to the effect of the electrostatic interaction between NPs and G5. The Royal Society of Chemistry 2021-04-09 /pmc/articles/PMC8697587/ /pubmed/35423851 http://dx.doi.org/10.1039/d1ra01157j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Shiba, Shunsuke
Ohta, Saki
Ohtani, Kazuya
Takahashi, Shota
Kato, Dai
Niwa, Osamu
Supporting effects of a N-doped carbon film electrode on an electrodeposited Ni@Ni(OH)(2) core–shell nanocatalyst in accelerating electrocatalytic oxidation of oligosaccharides
title Supporting effects of a N-doped carbon film electrode on an electrodeposited Ni@Ni(OH)(2) core–shell nanocatalyst in accelerating electrocatalytic oxidation of oligosaccharides
title_full Supporting effects of a N-doped carbon film electrode on an electrodeposited Ni@Ni(OH)(2) core–shell nanocatalyst in accelerating electrocatalytic oxidation of oligosaccharides
title_fullStr Supporting effects of a N-doped carbon film electrode on an electrodeposited Ni@Ni(OH)(2) core–shell nanocatalyst in accelerating electrocatalytic oxidation of oligosaccharides
title_full_unstemmed Supporting effects of a N-doped carbon film electrode on an electrodeposited Ni@Ni(OH)(2) core–shell nanocatalyst in accelerating electrocatalytic oxidation of oligosaccharides
title_short Supporting effects of a N-doped carbon film electrode on an electrodeposited Ni@Ni(OH)(2) core–shell nanocatalyst in accelerating electrocatalytic oxidation of oligosaccharides
title_sort supporting effects of a n-doped carbon film electrode on an electrodeposited ni@ni(oh)(2) core–shell nanocatalyst in accelerating electrocatalytic oxidation of oligosaccharides
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697587/
https://www.ncbi.nlm.nih.gov/pubmed/35423851
http://dx.doi.org/10.1039/d1ra01157j
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