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Change Law of Lower Limit of Gas Explosion at Ultra-High Temperatures

[Image: see text] During coal seam mining, a large amount of low-concentration mine gas will be produced, and it is the main utilization way to pass it into a thermal storage oxidation device to obtain heat energy. The thermal storage oxidation process is carried out in an ultra-high temperature env...

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Autores principales: Li, Xinyu, Chen, Haiyan, Li, Huaixing, Chen, Jinhua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697595/
https://www.ncbi.nlm.nih.gov/pubmed/34963992
http://dx.doi.org/10.1021/acsomega.1c05942
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author Li, Xinyu
Chen, Haiyan
Li, Huaixing
Chen, Jinhua
author_facet Li, Xinyu
Chen, Haiyan
Li, Huaixing
Chen, Jinhua
author_sort Li, Xinyu
collection PubMed
description [Image: see text] During coal seam mining, a large amount of low-concentration mine gas will be produced, and it is the main utilization way to pass it into a thermal storage oxidation device to obtain heat energy. The thermal storage oxidation process is carried out in an ultra-high temperature environment. The excessive gas concentration not only reduces the production efficiency but also presents an explosion hazard. To solve the abovementioned problems, the lower explosion limit of a low-concentration gas at ultra-high temperatures (900–1200 °C) was studied through a self-developed high-temperature explosion experimental device. Fluent software was used to simulate the reaction of a low-concentration gas in a high-temperature environment, and the experimental results were verified according to the maximum explosion pressure. Through analysis and discussion, the following are found: (1) the relationship between the instantaneous explosion pressure of the low-concentration gas and the gas concentration as well as the relationship between the maximum explosion pressure near the lower explosion limit and the gas concentration are in accordance with the Boltzmann function. (2) When the temperature rises from 900 to 1200 °C, the lower limit of gas explosion obtained from experiments is reduced from 2.33 to 1.36%. (3) The lower limit of gas explosion decreases with increasing temperature at ultra-high temperatures and the downward trend slows down, this is similar to the change rule of the lower limit of gas explosion at temperatures below 200 °C. These findings have certain practical significance for improving the utilization efficiency of the low-concentration gas in heat storage oxidation.
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spelling pubmed-86975952021-12-27 Change Law of Lower Limit of Gas Explosion at Ultra-High Temperatures Li, Xinyu Chen, Haiyan Li, Huaixing Chen, Jinhua ACS Omega [Image: see text] During coal seam mining, a large amount of low-concentration mine gas will be produced, and it is the main utilization way to pass it into a thermal storage oxidation device to obtain heat energy. The thermal storage oxidation process is carried out in an ultra-high temperature environment. The excessive gas concentration not only reduces the production efficiency but also presents an explosion hazard. To solve the abovementioned problems, the lower explosion limit of a low-concentration gas at ultra-high temperatures (900–1200 °C) was studied through a self-developed high-temperature explosion experimental device. Fluent software was used to simulate the reaction of a low-concentration gas in a high-temperature environment, and the experimental results were verified according to the maximum explosion pressure. Through analysis and discussion, the following are found: (1) the relationship between the instantaneous explosion pressure of the low-concentration gas and the gas concentration as well as the relationship between the maximum explosion pressure near the lower explosion limit and the gas concentration are in accordance with the Boltzmann function. (2) When the temperature rises from 900 to 1200 °C, the lower limit of gas explosion obtained from experiments is reduced from 2.33 to 1.36%. (3) The lower limit of gas explosion decreases with increasing temperature at ultra-high temperatures and the downward trend slows down, this is similar to the change rule of the lower limit of gas explosion at temperatures below 200 °C. These findings have certain practical significance for improving the utilization efficiency of the low-concentration gas in heat storage oxidation. American Chemical Society 2021-12-08 /pmc/articles/PMC8697595/ /pubmed/34963992 http://dx.doi.org/10.1021/acsomega.1c05942 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Li, Xinyu
Chen, Haiyan
Li, Huaixing
Chen, Jinhua
Change Law of Lower Limit of Gas Explosion at Ultra-High Temperatures
title Change Law of Lower Limit of Gas Explosion at Ultra-High Temperatures
title_full Change Law of Lower Limit of Gas Explosion at Ultra-High Temperatures
title_fullStr Change Law of Lower Limit of Gas Explosion at Ultra-High Temperatures
title_full_unstemmed Change Law of Lower Limit of Gas Explosion at Ultra-High Temperatures
title_short Change Law of Lower Limit of Gas Explosion at Ultra-High Temperatures
title_sort change law of lower limit of gas explosion at ultra-high temperatures
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697595/
https://www.ncbi.nlm.nih.gov/pubmed/34963992
http://dx.doi.org/10.1021/acsomega.1c05942
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