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Bulky Di(1-adamantyl)phosphinous Acid-Ligated Pd(II) Precatalysts for Suzuki Reactions of Unreactive Aryl Chlorides

[Image: see text] Di(1-adamantyl)phosphine oxide (SPO-Ad: Ad(2)P(V)(=O)H), a stable tautomer of di(1-adamantyl)phosphinous acid (PA-Ad: Ad(2)P(III)-OH), was employed to synthesize two new PA-Ad-coordinated complexes, POPd-Ad and POPd2-Ad. POPd-Ad was easily transformed from POPd2-Ad in acetonitrile,...

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Detalles Bibliográficos
Autores principales:	Xiao, He-Xin, Hsu, Wan-Yun, Liang, Siou-Wei, Guo, Yingjie, Lee, Wan-Ching, Lu, I-Chung, Chang, Yu-Chang
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697604/ https://www.ncbi.nlm.nih.gov/pubmed/34963994 http://dx.doi.org/10.1021/acsomega.1c06430

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