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Experimental Study on the Effects of Different Heating Rates on Coalbed Methane Desorption and an Analysis of Desorption Kinetics

[Image: see text] Heat injection is an effective way to enhance coalbed methane (CBM) extraction. However, at present, the best way to inject that heat is not clear. To determine how the heating rate affects methane desorption, desorption tests at constant high (95 °C) and low (20 °C) temperatures a...

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Autores principales: Wang, Zhijun, Zhu, Zhiguan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697617/
https://www.ncbi.nlm.nih.gov/pubmed/34963972
http://dx.doi.org/10.1021/acsomega.1c05562
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author Wang, Zhijun
Zhu, Zhiguan
author_facet Wang, Zhijun
Zhu, Zhiguan
author_sort Wang, Zhijun
collection PubMed
description [Image: see text] Heat injection is an effective way to enhance coalbed methane (CBM) extraction. However, at present, the best way to inject that heat is not clear. To determine how the heating rate affects methane desorption, desorption tests at constant high (95 °C) and low (20 °C) temperatures and at three different heating rates (0.3, 0.6, and 0.9 °C/min to 95 °C) were conducted. The desorption content (the volume of gas desorbed per mass of coal) and the desorption rate under the constant 95 °C temperature were greater than those under the constant 20 °C temperature. For the heating rate tests, the total desorption contents under heating rates of 0.3, 0.6, and 0.9 °C/min were 1.322 times, 1.115 times, and 1.095 times that from the constant 95 °C temperature tests, respectively. The final desorption contents from the entire desorption process under heating rates of 0.3, 0.6, and 0.9 °C/min were 1.42 times, 1.30 times, and 1.20 times that from the constant 95 °C temperature tests, respectively. In the early parts of the heating stages, the desorption rates under the three heating rate tests were lower than those under the constant 95 °C temperature tests. When the heating stages ended, the desorption rates under the three heating rates were greater than those under the constant 95 °C temperature tests. After the heating ended, the desorption rates decreased rapidly. A higher heating rate was correlated with a faster decrease in the desorption rate. Kinetic analysis showed that heating coal to a high temperature before methane is desorbed did not suppress the diffusion coefficient decrease. Heating during desorption prevented the diffusion coefficient decrease. A lower heating rate is correlated with a slower diffusion coefficient decrease. Low heating rates were more effective for desorbing methane. The heat injection in the later stage of desorption had a more significant effect on promoting methane desorption than did the early desorption stage heat injection. An equation for calculating the optimal heat injection rate was proposed. These findings will offer significant references for the selection of a suitable way to inject heat to enhance CBM extraction.
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spelling pubmed-86976172021-12-27 Experimental Study on the Effects of Different Heating Rates on Coalbed Methane Desorption and an Analysis of Desorption Kinetics Wang, Zhijun Zhu, Zhiguan ACS Omega [Image: see text] Heat injection is an effective way to enhance coalbed methane (CBM) extraction. However, at present, the best way to inject that heat is not clear. To determine how the heating rate affects methane desorption, desorption tests at constant high (95 °C) and low (20 °C) temperatures and at three different heating rates (0.3, 0.6, and 0.9 °C/min to 95 °C) were conducted. The desorption content (the volume of gas desorbed per mass of coal) and the desorption rate under the constant 95 °C temperature were greater than those under the constant 20 °C temperature. For the heating rate tests, the total desorption contents under heating rates of 0.3, 0.6, and 0.9 °C/min were 1.322 times, 1.115 times, and 1.095 times that from the constant 95 °C temperature tests, respectively. The final desorption contents from the entire desorption process under heating rates of 0.3, 0.6, and 0.9 °C/min were 1.42 times, 1.30 times, and 1.20 times that from the constant 95 °C temperature tests, respectively. In the early parts of the heating stages, the desorption rates under the three heating rate tests were lower than those under the constant 95 °C temperature tests. When the heating stages ended, the desorption rates under the three heating rates were greater than those under the constant 95 °C temperature tests. After the heating ended, the desorption rates decreased rapidly. A higher heating rate was correlated with a faster decrease in the desorption rate. Kinetic analysis showed that heating coal to a high temperature before methane is desorbed did not suppress the diffusion coefficient decrease. Heating during desorption prevented the diffusion coefficient decrease. A lower heating rate is correlated with a slower diffusion coefficient decrease. Low heating rates were more effective for desorbing methane. The heat injection in the later stage of desorption had a more significant effect on promoting methane desorption than did the early desorption stage heat injection. An equation for calculating the optimal heat injection rate was proposed. These findings will offer significant references for the selection of a suitable way to inject heat to enhance CBM extraction. American Chemical Society 2021-12-08 /pmc/articles/PMC8697617/ /pubmed/34963972 http://dx.doi.org/10.1021/acsomega.1c05562 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Wang, Zhijun
Zhu, Zhiguan
Experimental Study on the Effects of Different Heating Rates on Coalbed Methane Desorption and an Analysis of Desorption Kinetics
title Experimental Study on the Effects of Different Heating Rates on Coalbed Methane Desorption and an Analysis of Desorption Kinetics
title_full Experimental Study on the Effects of Different Heating Rates on Coalbed Methane Desorption and an Analysis of Desorption Kinetics
title_fullStr Experimental Study on the Effects of Different Heating Rates on Coalbed Methane Desorption and an Analysis of Desorption Kinetics
title_full_unstemmed Experimental Study on the Effects of Different Heating Rates on Coalbed Methane Desorption and an Analysis of Desorption Kinetics
title_short Experimental Study on the Effects of Different Heating Rates on Coalbed Methane Desorption and an Analysis of Desorption Kinetics
title_sort experimental study on the effects of different heating rates on coalbed methane desorption and an analysis of desorption kinetics
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697617/
https://www.ncbi.nlm.nih.gov/pubmed/34963972
http://dx.doi.org/10.1021/acsomega.1c05562
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