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White light employing luminescent engineered large (mega) Stokes shift molecules: a review
Large (mega) Stokes shift molecules have shown great potential in white light emission for optoelectronic applications, such as flat panel display technology, light-emitting diodes, photosensitizers, molecular probes, cellular and bioimaging, and other applications. This review aims to summarize rec...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697633/ https://www.ncbi.nlm.nih.gov/pubmed/35423891 http://dx.doi.org/10.1039/d1ra00129a |
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author | Mohd Yusof Chan, Nadia Nabihah Idris, Azila Zainal Abidin, Zul Hazrin Tajuddin, Hairul Anuar Abdullah, Zanariah |
author_facet | Mohd Yusof Chan, Nadia Nabihah Idris, Azila Zainal Abidin, Zul Hazrin Tajuddin, Hairul Anuar Abdullah, Zanariah |
author_sort | Mohd Yusof Chan, Nadia Nabihah |
collection | PubMed |
description | Large (mega) Stokes shift molecules have shown great potential in white light emission for optoelectronic applications, such as flat panel display technology, light-emitting diodes, photosensitizers, molecular probes, cellular and bioimaging, and other applications. This review aims to summarize recent developments of white light generation that incorporate a large Stokes shift component, key approaches to designing large Stokes shift molecules, perspectives on future opportunities, and remaining challenges confronting this emerging research field. After a brief introduction of feasible pathways in generating white light, exemplifications of large Stokes shift molecules as white light candidates from organic and inorganic-based materials are illustrated. Various possible ways to design such molecules have been revealed by integrating the photophysical mechanisms that are essential to produce red-shifted emission upon photoexcitation, such as excited state intramolecular proton transfer (ESIPT), intramolecular charge transfer (ICT), excited state geometrical relaxation or structural deformation, aggregation-induced emission (AIE) alongside the different formations of aggregates, interplay between monomer and excimer emission, host–guest interaction, and lastly metal to ligand charge transfer (MLCT) via harvesting triplet state. Furthermore, previously reported fluorescent materials are described and categorized based on luminescence behaviors on account of the Stokes shifts value. This review will serve as a rationalized introduction and reference for researchers who are interested in exploring large or mega Stokes shift molecules, and will motivate new strategies along with instigation of persistent efforts in this prominent subject area with great avenues. |
format | Online Article Text |
id | pubmed-8697633 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-86976332022-04-13 White light employing luminescent engineered large (mega) Stokes shift molecules: a review Mohd Yusof Chan, Nadia Nabihah Idris, Azila Zainal Abidin, Zul Hazrin Tajuddin, Hairul Anuar Abdullah, Zanariah RSC Adv Chemistry Large (mega) Stokes shift molecules have shown great potential in white light emission for optoelectronic applications, such as flat panel display technology, light-emitting diodes, photosensitizers, molecular probes, cellular and bioimaging, and other applications. This review aims to summarize recent developments of white light generation that incorporate a large Stokes shift component, key approaches to designing large Stokes shift molecules, perspectives on future opportunities, and remaining challenges confronting this emerging research field. After a brief introduction of feasible pathways in generating white light, exemplifications of large Stokes shift molecules as white light candidates from organic and inorganic-based materials are illustrated. Various possible ways to design such molecules have been revealed by integrating the photophysical mechanisms that are essential to produce red-shifted emission upon photoexcitation, such as excited state intramolecular proton transfer (ESIPT), intramolecular charge transfer (ICT), excited state geometrical relaxation or structural deformation, aggregation-induced emission (AIE) alongside the different formations of aggregates, interplay between monomer and excimer emission, host–guest interaction, and lastly metal to ligand charge transfer (MLCT) via harvesting triplet state. Furthermore, previously reported fluorescent materials are described and categorized based on luminescence behaviors on account of the Stokes shifts value. This review will serve as a rationalized introduction and reference for researchers who are interested in exploring large or mega Stokes shift molecules, and will motivate new strategies along with instigation of persistent efforts in this prominent subject area with great avenues. The Royal Society of Chemistry 2021-04-12 /pmc/articles/PMC8697633/ /pubmed/35423891 http://dx.doi.org/10.1039/d1ra00129a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Mohd Yusof Chan, Nadia Nabihah Idris, Azila Zainal Abidin, Zul Hazrin Tajuddin, Hairul Anuar Abdullah, Zanariah White light employing luminescent engineered large (mega) Stokes shift molecules: a review |
title | White light employing luminescent engineered large (mega) Stokes shift molecules: a review |
title_full | White light employing luminescent engineered large (mega) Stokes shift molecules: a review |
title_fullStr | White light employing luminescent engineered large (mega) Stokes shift molecules: a review |
title_full_unstemmed | White light employing luminescent engineered large (mega) Stokes shift molecules: a review |
title_short | White light employing luminescent engineered large (mega) Stokes shift molecules: a review |
title_sort | white light employing luminescent engineered large (mega) stokes shift molecules: a review |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697633/ https://www.ncbi.nlm.nih.gov/pubmed/35423891 http://dx.doi.org/10.1039/d1ra00129a |
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