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Divergent synthesis of flavones and flavanones from 2′-hydroxydihydrochalcones via palladium(ii)-catalyzed oxidative cyclization
Divergent and versatile synthetic routes to flavones and flavanones via efficient Pd(ii) catalysis are disclosed. These Pd(ii) catalyses expediently provide a variety of flavones and flavanones from 2′-hydroxydihydrochalcones as common intermediates, depending on oxidants and additives, via discrimi...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697754/ https://www.ncbi.nlm.nih.gov/pubmed/35423945 http://dx.doi.org/10.1039/d1ra01672e |
| _version_ | 1784620114321080320 |
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| author | Son, Seung Hwan Cho, Yang Yil Yoo, Hyung-Seok Lee, Soo Jin Kim, Young Min Jang, Hyu Jeong Kim, Dong Hwan Shin, Jeong-Won Kim, Nam-Jung |
| author_facet | Son, Seung Hwan Cho, Yang Yil Yoo, Hyung-Seok Lee, Soo Jin Kim, Young Min Jang, Hyu Jeong Kim, Dong Hwan Shin, Jeong-Won Kim, Nam-Jung |
| author_sort | Son, Seung Hwan |
| collection | PubMed |
| description | Divergent and versatile synthetic routes to flavones and flavanones via efficient Pd(ii) catalysis are disclosed. These Pd(ii) catalyses expediently provide a variety of flavones and flavanones from 2′-hydroxydihydrochalcones as common intermediates, depending on oxidants and additives, via discriminate oxidative cyclization sequences involving dehydrogenation, respectively, in a highly atom-economic manner. |
| format | Online Article Text |
| id | pubmed-8697754 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2021 |
| publisher | The Royal Society of Chemistry |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-86977542022-04-13 Divergent synthesis of flavones and flavanones from 2′-hydroxydihydrochalcones via palladium(ii)-catalyzed oxidative cyclization Son, Seung Hwan Cho, Yang Yil Yoo, Hyung-Seok Lee, Soo Jin Kim, Young Min Jang, Hyu Jeong Kim, Dong Hwan Shin, Jeong-Won Kim, Nam-Jung RSC Adv Chemistry Divergent and versatile synthetic routes to flavones and flavanones via efficient Pd(ii) catalysis are disclosed. These Pd(ii) catalyses expediently provide a variety of flavones and flavanones from 2′-hydroxydihydrochalcones as common intermediates, depending on oxidants and additives, via discriminate oxidative cyclization sequences involving dehydrogenation, respectively, in a highly atom-economic manner. The Royal Society of Chemistry 2021-04-13 /pmc/articles/PMC8697754/ /pubmed/35423945 http://dx.doi.org/10.1039/d1ra01672e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
| spellingShingle | Chemistry Son, Seung Hwan Cho, Yang Yil Yoo, Hyung-Seok Lee, Soo Jin Kim, Young Min Jang, Hyu Jeong Kim, Dong Hwan Shin, Jeong-Won Kim, Nam-Jung Divergent synthesis of flavones and flavanones from 2′-hydroxydihydrochalcones via palladium(ii)-catalyzed oxidative cyclization |
| title | Divergent synthesis of flavones and flavanones from 2′-hydroxydihydrochalcones via palladium(ii)-catalyzed oxidative cyclization |
| title_full | Divergent synthesis of flavones and flavanones from 2′-hydroxydihydrochalcones via palladium(ii)-catalyzed oxidative cyclization |
| title_fullStr | Divergent synthesis of flavones and flavanones from 2′-hydroxydihydrochalcones via palladium(ii)-catalyzed oxidative cyclization |
| title_full_unstemmed | Divergent synthesis of flavones and flavanones from 2′-hydroxydihydrochalcones via palladium(ii)-catalyzed oxidative cyclization |
| title_short | Divergent synthesis of flavones and flavanones from 2′-hydroxydihydrochalcones via palladium(ii)-catalyzed oxidative cyclization |
| title_sort | divergent synthesis of flavones and flavanones from 2′-hydroxydihydrochalcones via palladium(ii)-catalyzed oxidative cyclization |
| topic | Chemistry |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697754/ https://www.ncbi.nlm.nih.gov/pubmed/35423945 http://dx.doi.org/10.1039/d1ra01672e |
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