Copper(i) pyrimidine-2-thiolate cluster-based polymers as bifunctional visible-light-photocatalysts for chemoselective transfer hydrogenation of α,β-unsaturated carbonyls

The photoinduced chemoselective transfer hydrogenation of unsaturated carbonyls to allylic alcohols has been accomplished using cluster-based MOFs as bifunctional visible photocatalysts. Assemblies of hexanuclear clusters [Cu(6)(dmpymt)(6)] (1, Hdmpymt = 4,6-dimethylpyrimidine-2-thione) as metalloli...

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Detalles Bibliográficos
Autores principales: Zhang, Meng Juan, Young, David James, Ma, Ji Long, Shao, Guo Quan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697831/
https://www.ncbi.nlm.nih.gov/pubmed/35424070
http://dx.doi.org/10.1039/d1ra01102b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697831/
https://www.ncbi.nlm.nih.gov/pubmed/35424070
http://dx.doi.org/10.1039/d1ra01102b

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