Theoretical hydrogen bonding calculations and proton conduction for Eu(iii)-based metal–organic framework

A water-mediated proton-conducting Eu(iii)-MOF has been synthesized, which provides a stable proton transport channel that was confirmed by theoretical calculation. The investigation of proton conduction shows that the conductivity of Eu(iii)-MOF obtained at 353 K and 98% RH is 3.5 × 10(−3) S cm(−1)...

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Detalles Bibliográficos
Autores principales: Feng, Lu, Zeng, Tian-Yu, Hou, Hao-Bo, Zhou, Hong, Tian, Jian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8698213/
https://www.ncbi.nlm.nih.gov/pubmed/35423605
http://dx.doi.org/10.1039/d1ra01528a
Descripción
Sumario:A water-mediated proton-conducting Eu(iii)-MOF has been synthesized, which provides a stable proton transport channel that was confirmed by theoretical calculation. The investigation of proton conduction shows that the conductivity of Eu(iii)-MOF obtained at 353 K and 98% RH is 3.5 × 10(−3) S cm(−1), comparable to most of the Ln(iii)-MOF based proton conductors.

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