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High catalytic performance of Al–Pd–(Ru, Fe) icosahedral approximants for acetylene semi-hydrogenation

Three cubic crystalline icosahedral approximants (C phase: Al(72.0)Pd(16.4)Fe(11.6), P(40) phase: Al(72.0)Pd(16.4)Ru(11.6), P(20) phase: Al(70.0)Pd(22.3)Ru(7.7)) exhibit high ethylene selectivity of over 90% for hydrogenating acetylene at 150 °C. Moreover, the powdered P(20) also demonstrates a high...

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Detalles Bibliográficos
Autores principales: Abe, Keishi, Tsukuda, Ryota, Fujita, Nobuhisa, Kameoka, Satoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8698244/
https://www.ncbi.nlm.nih.gov/pubmed/35424072
http://dx.doi.org/10.1039/d1ra01958a