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Sorption and Textural Properties of Activated Carbon Derived from Charred Beech Wood

The aim of this study was to prepare activated carbon materials with different porous structures. For this purpose, the biomass precursor, beech wood, was carbonized in an inert atmosphere, and the obtained charcoal was physically activated using carbon dioxide at 1273 K. Different porous structures...

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Detalles Bibliográficos
Autores principales: Zgrzebnicki, Michal, Kałamaga, Agnieszka, Wrobel, Rafal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8703499/
https://www.ncbi.nlm.nih.gov/pubmed/34946688
http://dx.doi.org/10.3390/molecules26247604
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author Zgrzebnicki, Michal
Kałamaga, Agnieszka
Wrobel, Rafal
author_facet Zgrzebnicki, Michal
Kałamaga, Agnieszka
Wrobel, Rafal
author_sort Zgrzebnicki, Michal
collection PubMed
description The aim of this study was to prepare activated carbon materials with different porous structures. For this purpose, the biomass precursor, beech wood, was carbonized in an inert atmosphere, and the obtained charcoal was physically activated using carbon dioxide at 1273 K. Different porous structures were obtained by controlling the time of the activation process. Prepared materials were characterized in terms of textural (N(2) sorption at 77 K), structural (XRD), and sorption properties (CO(2), C(2)H(4), C(4)H(10)). The shortest activation time resulted in a mostly microporous structure, which provided a high sorption of CO(2). Increasing the activation time led to an increasing of the pores’ diameters. Therefore, the highest ethene uptake was obtained for the material with an intermediate activation time, while the highest butane uptake was obtained for the material with the highest activation time.
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spelling pubmed-87034992021-12-25 Sorption and Textural Properties of Activated Carbon Derived from Charred Beech Wood Zgrzebnicki, Michal Kałamaga, Agnieszka Wrobel, Rafal Molecules Article The aim of this study was to prepare activated carbon materials with different porous structures. For this purpose, the biomass precursor, beech wood, was carbonized in an inert atmosphere, and the obtained charcoal was physically activated using carbon dioxide at 1273 K. Different porous structures were obtained by controlling the time of the activation process. Prepared materials were characterized in terms of textural (N(2) sorption at 77 K), structural (XRD), and sorption properties (CO(2), C(2)H(4), C(4)H(10)). The shortest activation time resulted in a mostly microporous structure, which provided a high sorption of CO(2). Increasing the activation time led to an increasing of the pores’ diameters. Therefore, the highest ethene uptake was obtained for the material with an intermediate activation time, while the highest butane uptake was obtained for the material with the highest activation time. MDPI 2021-12-15 /pmc/articles/PMC8703499/ /pubmed/34946688 http://dx.doi.org/10.3390/molecules26247604 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zgrzebnicki, Michal
Kałamaga, Agnieszka
Wrobel, Rafal
Sorption and Textural Properties of Activated Carbon Derived from Charred Beech Wood
title Sorption and Textural Properties of Activated Carbon Derived from Charred Beech Wood
title_full Sorption and Textural Properties of Activated Carbon Derived from Charred Beech Wood
title_fullStr Sorption and Textural Properties of Activated Carbon Derived from Charred Beech Wood
title_full_unstemmed Sorption and Textural Properties of Activated Carbon Derived from Charred Beech Wood
title_short Sorption and Textural Properties of Activated Carbon Derived from Charred Beech Wood
title_sort sorption and textural properties of activated carbon derived from charred beech wood
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8703499/
https://www.ncbi.nlm.nih.gov/pubmed/34946688
http://dx.doi.org/10.3390/molecules26247604
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