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Effect of Borpolymer on Mechanical and Structural Parameters of Ultra-High Molecular Weight Polyethylene

The paper presents the results of studying the effect of borpolymer (BP) on the mechanical properties, structure, and thermodynamic parameters of ultra-high molecular weight polyethylene (UHMWPE). Changes in the mechanical characteristics of polymer composites material (PCM) are confirmed and comple...

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Autores principales: Danilova, Sakhayana N., Dyakonov, Afanasy A., Vasilev, Andrey P., Okhlopkova, Aitalina A., Tuisov, Aleksei G., Kychkin, Anatoly K., Kychkin, Aisen A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8703745/
https://www.ncbi.nlm.nih.gov/pubmed/34947747
http://dx.doi.org/10.3390/nano11123398
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author Danilova, Sakhayana N.
Dyakonov, Afanasy A.
Vasilev, Andrey P.
Okhlopkova, Aitalina A.
Tuisov, Aleksei G.
Kychkin, Anatoly K.
Kychkin, Aisen A.
author_facet Danilova, Sakhayana N.
Dyakonov, Afanasy A.
Vasilev, Andrey P.
Okhlopkova, Aitalina A.
Tuisov, Aleksei G.
Kychkin, Anatoly K.
Kychkin, Aisen A.
author_sort Danilova, Sakhayana N.
collection PubMed
description The paper presents the results of studying the effect of borpolymer (BP) on the mechanical properties, structure, and thermodynamic parameters of ultra-high molecular weight polyethylene (UHMWPE). Changes in the mechanical characteristics of polymer composites material (PCM) are confirmed and complemented by structural studies. X-ray crystallography (XRC), differential scanning calorimetry (DSC), scanning electron microscopy (SEM), and infrared spectroscopy (IR) were used to study the melting point, morphology and composition of the filler, which corresponds to the composition and data of the certificate of the synthesized BP. Tensile and compressive mechanical tests were carried out in accordance with generally accepted standards (ASTM). It is shown that BP is an effective modifier for UHMWPE, contributing to a significant increase in the deformation and strength characteristics of the composite: tensile strength of PCM by 56%, elongation at break by 28% and compressive strength at 10% strain by 65% compared to the initial UHMWPE, due to intensive changes in the supramolecular structure of the matrix. Structural studies revealed that BP does not chemically interact with UHMWPE, but due to its high adhesion to the polymer, it acts as a reinforcing filler. SEM was used to establish the formation of a spherulite supramolecular structure of polymer composites.
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spelling pubmed-87037452021-12-25 Effect of Borpolymer on Mechanical and Structural Parameters of Ultra-High Molecular Weight Polyethylene Danilova, Sakhayana N. Dyakonov, Afanasy A. Vasilev, Andrey P. Okhlopkova, Aitalina A. Tuisov, Aleksei G. Kychkin, Anatoly K. Kychkin, Aisen A. Nanomaterials (Basel) Article The paper presents the results of studying the effect of borpolymer (BP) on the mechanical properties, structure, and thermodynamic parameters of ultra-high molecular weight polyethylene (UHMWPE). Changes in the mechanical characteristics of polymer composites material (PCM) are confirmed and complemented by structural studies. X-ray crystallography (XRC), differential scanning calorimetry (DSC), scanning electron microscopy (SEM), and infrared spectroscopy (IR) were used to study the melting point, morphology and composition of the filler, which corresponds to the composition and data of the certificate of the synthesized BP. Tensile and compressive mechanical tests were carried out in accordance with generally accepted standards (ASTM). It is shown that BP is an effective modifier for UHMWPE, contributing to a significant increase in the deformation and strength characteristics of the composite: tensile strength of PCM by 56%, elongation at break by 28% and compressive strength at 10% strain by 65% compared to the initial UHMWPE, due to intensive changes in the supramolecular structure of the matrix. Structural studies revealed that BP does not chemically interact with UHMWPE, but due to its high adhesion to the polymer, it acts as a reinforcing filler. SEM was used to establish the formation of a spherulite supramolecular structure of polymer composites. MDPI 2021-12-15 /pmc/articles/PMC8703745/ /pubmed/34947747 http://dx.doi.org/10.3390/nano11123398 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Danilova, Sakhayana N.
Dyakonov, Afanasy A.
Vasilev, Andrey P.
Okhlopkova, Aitalina A.
Tuisov, Aleksei G.
Kychkin, Anatoly K.
Kychkin, Aisen A.
Effect of Borpolymer on Mechanical and Structural Parameters of Ultra-High Molecular Weight Polyethylene
title Effect of Borpolymer on Mechanical and Structural Parameters of Ultra-High Molecular Weight Polyethylene
title_full Effect of Borpolymer on Mechanical and Structural Parameters of Ultra-High Molecular Weight Polyethylene
title_fullStr Effect of Borpolymer on Mechanical and Structural Parameters of Ultra-High Molecular Weight Polyethylene
title_full_unstemmed Effect of Borpolymer on Mechanical and Structural Parameters of Ultra-High Molecular Weight Polyethylene
title_short Effect of Borpolymer on Mechanical and Structural Parameters of Ultra-High Molecular Weight Polyethylene
title_sort effect of borpolymer on mechanical and structural parameters of ultra-high molecular weight polyethylene
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8703745/
https://www.ncbi.nlm.nih.gov/pubmed/34947747
http://dx.doi.org/10.3390/nano11123398
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