Cargando…
Pitting Corrosion Behavior and Surface Microstructure of Copper Strips When Rolled with Oil-in-Water Emulsions
Copper strips experience severe corrosion when rolled with an oil-in-water (O/W) emulsions lubricant. The effects of rolling reduction on the pitting corrosion behavior and surface microstructure of Cu strips were studied in detail using electrochemical measurements and electron back scattered diffr...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8704875/ https://www.ncbi.nlm.nih.gov/pubmed/34947504 http://dx.doi.org/10.3390/ma14247911 |
_version_ | 1784621811081674752 |
---|---|
author | Yan, Xudong Sun, Jianlin |
author_facet | Yan, Xudong Sun, Jianlin |
author_sort | Yan, Xudong |
collection | PubMed |
description | Copper strips experience severe corrosion when rolled with an oil-in-water (O/W) emulsions lubricant. The effects of rolling reduction on the pitting corrosion behavior and surface microstructure of Cu strips were studied in detail using electrochemical measurements and electron back scattered diffraction (EBSD) analysis. It was found that the corrosion current densities of the rolled Cu strips increased with accumulated reduction, which also lowered the pitting potentials and weakened their corrosion resistances. Therefore, the corrosive tendency of Cu strips under different rolling reductions (ε) followed the order of ε(0%) < ε(20.7%) < ε(50.6%) < ε(77.3%). The Cu surface easily reacted with chlorine, sulfur, and carbon components from O/W emulsions to generate pitting corrosion. Under the interactive effect of pitting corrosion and stress corrosion, pits expanded along the rolling direction. The aggregation of anions in surface defects, such as dislocations, metastable pits, and microcracks, further accelerated the pitting corrosion of the surface. |
format | Online Article Text |
id | pubmed-8704875 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-87048752021-12-25 Pitting Corrosion Behavior and Surface Microstructure of Copper Strips When Rolled with Oil-in-Water Emulsions Yan, Xudong Sun, Jianlin Materials (Basel) Article Copper strips experience severe corrosion when rolled with an oil-in-water (O/W) emulsions lubricant. The effects of rolling reduction on the pitting corrosion behavior and surface microstructure of Cu strips were studied in detail using electrochemical measurements and electron back scattered diffraction (EBSD) analysis. It was found that the corrosion current densities of the rolled Cu strips increased with accumulated reduction, which also lowered the pitting potentials and weakened their corrosion resistances. Therefore, the corrosive tendency of Cu strips under different rolling reductions (ε) followed the order of ε(0%) < ε(20.7%) < ε(50.6%) < ε(77.3%). The Cu surface easily reacted with chlorine, sulfur, and carbon components from O/W emulsions to generate pitting corrosion. Under the interactive effect of pitting corrosion and stress corrosion, pits expanded along the rolling direction. The aggregation of anions in surface defects, such as dislocations, metastable pits, and microcracks, further accelerated the pitting corrosion of the surface. MDPI 2021-12-20 /pmc/articles/PMC8704875/ /pubmed/34947504 http://dx.doi.org/10.3390/ma14247911 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Yan, Xudong Sun, Jianlin Pitting Corrosion Behavior and Surface Microstructure of Copper Strips When Rolled with Oil-in-Water Emulsions |
title | Pitting Corrosion Behavior and Surface Microstructure of Copper Strips When Rolled with Oil-in-Water Emulsions |
title_full | Pitting Corrosion Behavior and Surface Microstructure of Copper Strips When Rolled with Oil-in-Water Emulsions |
title_fullStr | Pitting Corrosion Behavior and Surface Microstructure of Copper Strips When Rolled with Oil-in-Water Emulsions |
title_full_unstemmed | Pitting Corrosion Behavior and Surface Microstructure of Copper Strips When Rolled with Oil-in-Water Emulsions |
title_short | Pitting Corrosion Behavior and Surface Microstructure of Copper Strips When Rolled with Oil-in-Water Emulsions |
title_sort | pitting corrosion behavior and surface microstructure of copper strips when rolled with oil-in-water emulsions |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8704875/ https://www.ncbi.nlm.nih.gov/pubmed/34947504 http://dx.doi.org/10.3390/ma14247911 |
work_keys_str_mv | AT yanxudong pittingcorrosionbehaviorandsurfacemicrostructureofcopperstripswhenrolledwithoilinwateremulsions AT sunjianlin pittingcorrosionbehaviorandsurfacemicrostructureofcopperstripswhenrolledwithoilinwateremulsions |