Organocatalytic Ring-Opening Polymerization of ε-Caprolactone Using bis(N-(N′-butylimidazolium)alkane Dicationic Ionic Liquids as the Metal-Free Catalysts: Polymer Synthesis, Kinetics and DFT Mechanistic Study

In this work, we successfully synthesized high thermal stable 1,n-bis(N-(N′-butylimidazolium)alkane bishexafluorophosphates (1,n-bis[Bim][PF(6)], n = 4, 6, 8, and 10) catalysts in 55–70% yields from imidazole which were applied as non-toxic DILs catalysts with 1-butanol as initiator for the bulk ROP...

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Detalles Bibliográficos
Autores principales: Cheechana, Nathaporn, Benchaphanthawee, Wachara, Akkravijitkul, Natthapol, Rithchumpon, Puracheth, Junpirom, Thiti, Limwanich, Wanich, Punyodom, Winita, Kungwan, Nawee, Ngaojampa, Chanisorn, Thavornyutikarn, Praput, Meepowpan, Puttinan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8705680/
https://www.ncbi.nlm.nih.gov/pubmed/34960841
http://dx.doi.org/10.3390/polym13244290

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