Co(3)O(4) Nanoneedle Array Grown on Carbon Fiber Paper for Air Cathodes towards Flexible and Rechargeable Zn–Air Batteries

An economical and efficient method is developed for preparing flexible cathodes. In this work, a dense mesoporous Co(3)O(4) layer was first hydrothermally grown in situ on the surface of chopped carbon fibers (CFs), and then carbon fiber paper (Co(3)O(4)/CP) was prepared by a wet papermaking process as a flexible zinc-air battery (ZAB). The high-performance air cathode utilizes the high specific surface area of a single chopped carbon fiber, which is conducive to the deposition and adhesion of the Co(3)O(4) layer. Through the wet papermaking process, Co(3)O(4)/CP has ultra-thin, high mechanical stability and excellent electrical conductivity. In addition, the assembled ZAB exhibits relatively excellent electrochemical performance, with a continuous cycle of more than 180 times at a current density of 2 mA·cm(−2). The zinc-air battery can maintain a close fit and work stably and efficiently even under high bending conditions. This process of combining single carbon fibers to prepare ultra-thin, high-density, high-conductivity carbon fiber paper through a papermaking process has huge application potential in the field of flexible wearables.