Solubility of Hybrid Halide Perovskites in DMF and DMSO

Solution methods remain the most popular means for the fabrication of hybrid halide perovskites. However, the solubility of hybrid perovskites has not yet been quantitively investigated. In this study, we present accurate solubility data for MAPbI(3), FAPbI(3), MAPbBr(3) and FAPbBr(3) in the two mos...

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Autores principales: Petrov, Andrey A., Ordinartsev, Artem A., Fateev, Sergey A., Goodilin, Eugene A., Tarasov, Alexey B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8706401/
https://www.ncbi.nlm.nih.gov/pubmed/34946624
http://dx.doi.org/10.3390/molecules26247541
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author Petrov, Andrey A.
Ordinartsev, Artem A.
Fateev, Sergey A.
Goodilin, Eugene A.
Tarasov, Alexey B.
author_facet Petrov, Andrey A.
Ordinartsev, Artem A.
Fateev, Sergey A.
Goodilin, Eugene A.
Tarasov, Alexey B.
author_sort Petrov, Andrey A.
collection PubMed
description Solution methods remain the most popular means for the fabrication of hybrid halide perovskites. However, the solubility of hybrid perovskites has not yet been quantitively investigated. In this study, we present accurate solubility data for MAPbI(3), FAPbI(3), MAPbBr(3) and FAPbBr(3) in the two most widely used solvents, DMF and DMSO, and demonstrate huge differences in the solubility behavior depending on the solution compositions. By analyzing the donor numbers of the solvents and halide anions, we rationalize the differences in the solubility behavior of hybrid perovskites with various compositions, in order to take a step forward in the search for better processing conditions of hybrid perovskites for solar cells and optoelectronics.
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spelling pubmed-87064012021-12-25 Solubility of Hybrid Halide Perovskites in DMF and DMSO Petrov, Andrey A. Ordinartsev, Artem A. Fateev, Sergey A. Goodilin, Eugene A. Tarasov, Alexey B. Molecules Communication Solution methods remain the most popular means for the fabrication of hybrid halide perovskites. However, the solubility of hybrid perovskites has not yet been quantitively investigated. In this study, we present accurate solubility data for MAPbI(3), FAPbI(3), MAPbBr(3) and FAPbBr(3) in the two most widely used solvents, DMF and DMSO, and demonstrate huge differences in the solubility behavior depending on the solution compositions. By analyzing the donor numbers of the solvents and halide anions, we rationalize the differences in the solubility behavior of hybrid perovskites with various compositions, in order to take a step forward in the search for better processing conditions of hybrid perovskites for solar cells and optoelectronics. MDPI 2021-12-13 /pmc/articles/PMC8706401/ /pubmed/34946624 http://dx.doi.org/10.3390/molecules26247541 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Petrov, Andrey A.
Ordinartsev, Artem A.
Fateev, Sergey A.
Goodilin, Eugene A.
Tarasov, Alexey B.
Solubility of Hybrid Halide Perovskites in DMF and DMSO
title Solubility of Hybrid Halide Perovskites in DMF and DMSO
title_full Solubility of Hybrid Halide Perovskites in DMF and DMSO
title_fullStr Solubility of Hybrid Halide Perovskites in DMF and DMSO
title_full_unstemmed Solubility of Hybrid Halide Perovskites in DMF and DMSO
title_short Solubility of Hybrid Halide Perovskites in DMF and DMSO
title_sort solubility of hybrid halide perovskites in dmf and dmso
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8706401/
https://www.ncbi.nlm.nih.gov/pubmed/34946624
http://dx.doi.org/10.3390/molecules26247541
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