Copolymerization of Ethylene with Selected Vinyl Monomers Catalyzed by Group 4 Metal and Vanadium Complexes with Multidentate Ligands: A Short Review

This paper gives a short overview of homogeneous post-metallocene catalysts based on group 4 metal and vanadium complexes bearing multidentate ligands. It summarizes the catalytic behavior of those catalysts in copolymerization of ethylene with 1-olefins, with styrenic monomers and with α,ω-alkenols...

Descripción completa

Detalles Bibliográficos
Autores principales: Białek, Marzena, Fryga, Julia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8708287/
https://www.ncbi.nlm.nih.gov/pubmed/34961007
http://dx.doi.org/10.3390/polym13244456
_version_ 1784622646470639616
author Białek, Marzena
Fryga, Julia
author_facet Białek, Marzena
Fryga, Julia
author_sort Białek, Marzena
collection PubMed
description This paper gives a short overview of homogeneous post-metallocene catalysts based on group 4 metal and vanadium complexes bearing multidentate ligands. It summarizes the catalytic behavior of those catalysts in copolymerization of ethylene with 1-olefins, with styrenic monomers and with α,ω-alkenols. The review is focused on finding correlations between the structure of a complex, its catalyst activity and comonomer incorporation ability, as well as the microstructure of the copolymer chains.
format Online
Article
Text
id pubmed-8708287
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-87082872021-12-25 Copolymerization of Ethylene with Selected Vinyl Monomers Catalyzed by Group 4 Metal and Vanadium Complexes with Multidentate Ligands: A Short Review Białek, Marzena Fryga, Julia Polymers (Basel) Review This paper gives a short overview of homogeneous post-metallocene catalysts based on group 4 metal and vanadium complexes bearing multidentate ligands. It summarizes the catalytic behavior of those catalysts in copolymerization of ethylene with 1-olefins, with styrenic monomers and with α,ω-alkenols. The review is focused on finding correlations between the structure of a complex, its catalyst activity and comonomer incorporation ability, as well as the microstructure of the copolymer chains. MDPI 2021-12-19 /pmc/articles/PMC8708287/ /pubmed/34961007 http://dx.doi.org/10.3390/polym13244456 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Białek, Marzena
Fryga, Julia
Copolymerization of Ethylene with Selected Vinyl Monomers Catalyzed by Group 4 Metal and Vanadium Complexes with Multidentate Ligands: A Short Review
title Copolymerization of Ethylene with Selected Vinyl Monomers Catalyzed by Group 4 Metal and Vanadium Complexes with Multidentate Ligands: A Short Review
title_full Copolymerization of Ethylene with Selected Vinyl Monomers Catalyzed by Group 4 Metal and Vanadium Complexes with Multidentate Ligands: A Short Review
title_fullStr Copolymerization of Ethylene with Selected Vinyl Monomers Catalyzed by Group 4 Metal and Vanadium Complexes with Multidentate Ligands: A Short Review
title_full_unstemmed Copolymerization of Ethylene with Selected Vinyl Monomers Catalyzed by Group 4 Metal and Vanadium Complexes with Multidentate Ligands: A Short Review
title_short Copolymerization of Ethylene with Selected Vinyl Monomers Catalyzed by Group 4 Metal and Vanadium Complexes with Multidentate Ligands: A Short Review
title_sort copolymerization of ethylene with selected vinyl monomers catalyzed by group 4 metal and vanadium complexes with multidentate ligands: a short review
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8708287/
https://www.ncbi.nlm.nih.gov/pubmed/34961007
http://dx.doi.org/10.3390/polym13244456
work_keys_str_mv AT białekmarzena copolymerizationofethylenewithselectedvinylmonomerscatalyzedbygroup4metalandvanadiumcomplexeswithmultidentateligandsashortreview
AT frygajulia copolymerizationofethylenewithselectedvinylmonomerscatalyzedbygroup4metalandvanadiumcomplexeswithmultidentateligandsashortreview

Ejemplares similares