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A Sulfonated Polyimide/Nafion Blend Membrane with High Proton Selectivity and Remarkable Stability for Vanadium Redox Flow Battery

A sulfonated polyimide (SPI)/Nafion blend membrane composed of a designed and synthesized SPI polymer and the commercial Nafion polymer is prepared by a facile solution casting method for vanadium redox flow battery (VRFB). Similar molecular structures of both SPI and Nafion provide good compatibili...

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Detalles Bibliográficos
Autores principales: Li, Jinchao, Liu, Jun, Xu, Wenjie, Long, Jun, Huang, Wenheng, He, Zhen, Liu, Suqin, Zhang, Yaping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8708936/
https://www.ncbi.nlm.nih.gov/pubmed/34940447
http://dx.doi.org/10.3390/membranes11120946
Descripción
Sumario:A sulfonated polyimide (SPI)/Nafion blend membrane composed of a designed and synthesized SPI polymer and the commercial Nafion polymer is prepared by a facile solution casting method for vanadium redox flow battery (VRFB). Similar molecular structures of both SPI and Nafion provide good compatibility and complementarity of the blend membrane. ATR-FTIR, (1)H-NMR, AFM, and SEM are used to gain insights on the chemical structure and morphology of the blend membrane. Fortunately, the chemical stability of the SPI/Nafion blend membrane is effectively improved compared with reported SPI-based membranes for VRFB applications. In cycling charge-discharge tests, the VRFB with the as-prepared SPI/Nafion blend membrane shows excellent battery efficiencies and operational stability. Above results indicate that the SPI/Nafion blend membrane is a promising candidate for VRFB application. This work opens up a new possibility for fabricating high-performance SPI-based blend membrane by introduction of a polymer with a similar molecular structure and special functional groups into the SPI polymer.