Leveraging of Sulfur Anions in Photoinduced Molecular Transformations

[Image: see text] This perspective describes recent advances in the use of sulfur anions to promote molecular transformations under irradiation with visible light. The topics are classified by the following reaction modes performed by the key sulfur anions: (1) C–S coupling via electron donor–accept...

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Autores principales: Li, Haoyu, Liu, Yuliang, Chiba, Shunsuke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8715496/
https://www.ncbi.nlm.nih.gov/pubmed/34977884
http://dx.doi.org/10.1021/jacsau.1c00363
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author Li, Haoyu
Liu, Yuliang
Chiba, Shunsuke
author_facet Li, Haoyu
Liu, Yuliang
Chiba, Shunsuke
author_sort Li, Haoyu
collection PubMed
description [Image: see text] This perspective describes recent advances in the use of sulfur anions to promote molecular transformations under irradiation with visible light. The topics are classified by the following reaction modes performed by the key sulfur anions: (1) C–S coupling via electron donor–acceptor (EDA) interactions, (2) photoinduced molecular transformation via sulfur anion EDA catalysis, (3) sulfur anions as photoredox and hydrogen atom transfer (HAT) catalysts, and 4) dithiocarbamate and xanthate as nucleophilic catalysts for photoinduced radical cascade reactions.
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spelling pubmed-87154962021-12-30 Leveraging of Sulfur Anions in Photoinduced Molecular Transformations Li, Haoyu Liu, Yuliang Chiba, Shunsuke JACS Au [Image: see text] This perspective describes recent advances in the use of sulfur anions to promote molecular transformations under irradiation with visible light. The topics are classified by the following reaction modes performed by the key sulfur anions: (1) C–S coupling via electron donor–acceptor (EDA) interactions, (2) photoinduced molecular transformation via sulfur anion EDA catalysis, (3) sulfur anions as photoredox and hydrogen atom transfer (HAT) catalysts, and 4) dithiocarbamate and xanthate as nucleophilic catalysts for photoinduced radical cascade reactions. American Chemical Society 2021-10-20 /pmc/articles/PMC8715496/ /pubmed/34977884 http://dx.doi.org/10.1021/jacsau.1c00363 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Li, Haoyu
Liu, Yuliang
Chiba, Shunsuke
Leveraging of Sulfur Anions in Photoinduced Molecular Transformations
title Leveraging of Sulfur Anions in Photoinduced Molecular Transformations
title_full Leveraging of Sulfur Anions in Photoinduced Molecular Transformations
title_fullStr Leveraging of Sulfur Anions in Photoinduced Molecular Transformations
title_full_unstemmed Leveraging of Sulfur Anions in Photoinduced Molecular Transformations
title_short Leveraging of Sulfur Anions in Photoinduced Molecular Transformations
title_sort leveraging of sulfur anions in photoinduced molecular transformations
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8715496/
https://www.ncbi.nlm.nih.gov/pubmed/34977884
http://dx.doi.org/10.1021/jacsau.1c00363
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