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K(3)V(2)O(3)F(4)(IO(3))(3): a high-performance SHG crystal containing both five and six-coordinated V(5+) cations
The combination of d(0) transition metal oxofluorides with iodate anions helps to synthesize polar crystals. Herein, a novel polar crystal, K(3)V(2)O(3)F(4)(IO(3))(3), which is the first metal vanadium iodate with two types of V(5+)-centered polyhedra (VO(4)F(2) octahedron and VO(3)F(2) trigonal bip...
Autores principales: | Chen, Jin, Hu, Chun-Li, Lin, Yi-Lin, Chen, Yan, Chen, Qian-Qian, Mao, Jiang-Gao |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8729798/ https://www.ncbi.nlm.nih.gov/pubmed/35126977 http://dx.doi.org/10.1039/d1sc06026k |
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