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Covalency between the uranyl ion and dithiophosphinate by sulfur K-edge X-ray absorption spectroscopy and density functional theory

The dithiophosphinic acids (HS(2)PR (2)) have been used for the selective separation of trivalent actinides (An(III)) from lanthanides (Ln(III)) over the past decades. The substituents on the dithiophosphinic acids dramatically impact the separation performance, but the mechanism is still open for...

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Detalles Bibliográficos
Autores principales:	Zhang, Yusheng, Duan, Wuhua, Wang, Qiang, Zheng, Lei, Wang, Jianchen, Chen, Jing, Sun, Taoxiang
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2022
Materias:	Actinide Physics and Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8733989/ https://www.ncbi.nlm.nih.gov/pubmed/34985418 http://dx.doi.org/10.1107/S160057752101198X

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