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Mechanism of Diiron Hydrogenase Complexes Controlled by Nature of Bridging Dithiolate Ligand

Bio‐inorganic complexes inspired by hydrogenase enzymes are designed to catalyze the hydrogen evolution reaction (HER). A series of new diiron hydrogenase mimic complexes with one or two terminal tris(4‐methoxyphenyl)phosphine and different μ‐bridging dithiolate ligands and show catalytic activity t...

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Detalles Bibliográficos
Autores principales: Natarajan, Mookan, Kumar, Naveen, Joshi, Meenakshi, Stein, Matthias, Kaur‐Ghumaan, Sandeep
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8734113/
https://www.ncbi.nlm.nih.gov/pubmed/34981908
http://dx.doi.org/10.1002/open.202100238