Cargando…
Crystal structures and Hirshfeld surface analyses of bis(4,5-dihydrofuran-2-yl)dimethylsilane and (4,5-dihydrofuran-2-yl)(methyl)diphenylsilane
The title compounds, C(10)H(16)O(2)Si (1) and C(17)H(18)OSi (2), are classified as dihydrofurylsilanes, which show great potential as building blocks for various functionalized silanes. They both crystallize in the space group P [Image: see text] in the triclinic crystal system. Analyses of the Hi...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8739194/ https://www.ncbi.nlm.nih.gov/pubmed/35079417 http://dx.doi.org/10.1107/S2056989021012548 |
_version_ | 1784629050116931584 |
---|---|
author | Schmidt, Annika Krupp, Anna Barth, Eva Rebecca Strohmann, Carsten |
author_facet | Schmidt, Annika Krupp, Anna Barth, Eva Rebecca Strohmann, Carsten |
author_sort | Schmidt, Annika |
collection | PubMed |
description | The title compounds, C(10)H(16)O(2)Si (1) and C(17)H(18)OSi (2), are classified as dihydrofurylsilanes, which show great potential as building blocks for various functionalized silanes. They both crystallize in the space group P [Image: see text] in the triclinic crystal system. Analyses of the Hirshfeld surfaces show packing-determining interactions for both compounds, resulting in a polymeric chain along the [011] for silane 1 and a layered-interconnected structure along the b-axis direction for silane 2. |
format | Online Article Text |
id | pubmed-8739194 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-87391942022-01-24 Crystal structures and Hirshfeld surface analyses of bis(4,5-dihydrofuran-2-yl)dimethylsilane and (4,5-dihydrofuran-2-yl)(methyl)diphenylsilane Schmidt, Annika Krupp, Anna Barth, Eva Rebecca Strohmann, Carsten Acta Crystallogr E Crystallogr Commun Research Communications The title compounds, C(10)H(16)O(2)Si (1) and C(17)H(18)OSi (2), are classified as dihydrofurylsilanes, which show great potential as building blocks for various functionalized silanes. They both crystallize in the space group P [Image: see text] in the triclinic crystal system. Analyses of the Hirshfeld surfaces show packing-determining interactions for both compounds, resulting in a polymeric chain along the [011] for silane 1 and a layered-interconnected structure along the b-axis direction for silane 2. International Union of Crystallography 2022-01-01 /pmc/articles/PMC8739194/ /pubmed/35079417 http://dx.doi.org/10.1107/S2056989021012548 Text en © Schmidt et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Schmidt, Annika Krupp, Anna Barth, Eva Rebecca Strohmann, Carsten Crystal structures and Hirshfeld surface analyses of bis(4,5-dihydrofuran-2-yl)dimethylsilane and (4,5-dihydrofuran-2-yl)(methyl)diphenylsilane |
title | Crystal structures and Hirshfeld surface analyses of bis(4,5-dihydrofuran-2-yl)dimethylsilane and (4,5-dihydrofuran-2-yl)(methyl)diphenylsilane |
title_full | Crystal structures and Hirshfeld surface analyses of bis(4,5-dihydrofuran-2-yl)dimethylsilane and (4,5-dihydrofuran-2-yl)(methyl)diphenylsilane |
title_fullStr | Crystal structures and Hirshfeld surface analyses of bis(4,5-dihydrofuran-2-yl)dimethylsilane and (4,5-dihydrofuran-2-yl)(methyl)diphenylsilane |
title_full_unstemmed | Crystal structures and Hirshfeld surface analyses of bis(4,5-dihydrofuran-2-yl)dimethylsilane and (4,5-dihydrofuran-2-yl)(methyl)diphenylsilane |
title_short | Crystal structures and Hirshfeld surface analyses of bis(4,5-dihydrofuran-2-yl)dimethylsilane and (4,5-dihydrofuran-2-yl)(methyl)diphenylsilane |
title_sort | crystal structures and hirshfeld surface analyses of bis(4,5-dihydrofuran-2-yl)dimethylsilane and (4,5-dihydrofuran-2-yl)(methyl)diphenylsilane |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8739194/ https://www.ncbi.nlm.nih.gov/pubmed/35079417 http://dx.doi.org/10.1107/S2056989021012548 |
work_keys_str_mv | AT schmidtannika crystalstructuresandhirshfeldsurfaceanalysesofbis45dihydrofuran2yldimethylsilaneand45dihydrofuran2ylmethyldiphenylsilane AT kruppanna crystalstructuresandhirshfeldsurfaceanalysesofbis45dihydrofuran2yldimethylsilaneand45dihydrofuran2ylmethyldiphenylsilane AT barthevarebecca crystalstructuresandhirshfeldsurfaceanalysesofbis45dihydrofuran2yldimethylsilaneand45dihydrofuran2ylmethyldiphenylsilane AT strohmanncarsten crystalstructuresandhirshfeldsurfaceanalysesofbis45dihydrofuran2yldimethylsilaneand45dihydrofuran2ylmethyldiphenylsilane |