Synthesis and crystal structure of (E)-2-benzyl-1,3-di­phenyl­iso­thio­uronium iodide

In the title mol­ecular salt, C(20)H(19)N(2)S(+)·I(−), prepared by the reaction of 1,3-di­phenyl­thio­urea and benzyl iodide, the C—S—C thio­ether bond angle is 101.66 (9)° and electrons are delocalized over the N(+)= C—N skeleton. The dihedral angle between the aromatic rings attached to the N atom...

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Autores principales: Kang, Sungmin, Kim, Taek Hyeon, Kwak, Chee-Hun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8739197/
https://www.ncbi.nlm.nih.gov/pubmed/35079424
http://dx.doi.org/10.1107/S2056989021013086
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author Kang, Sungmin
Kim, Taek Hyeon
Kwak, Chee-Hun
author_facet Kang, Sungmin
Kim, Taek Hyeon
Kwak, Chee-Hun
author_sort Kang, Sungmin
collection PubMed
description In the title mol­ecular salt, C(20)H(19)N(2)S(+)·I(−), prepared by the reaction of 1,3-di­phenyl­thio­urea and benzyl iodide, the C—S—C thio­ether bond angle is 101.66 (9)° and electrons are delocalized over the N(+)= C—N skeleton. The dihedral angle between the aromatic rings attached to the N atoms is 40.60 (9)°. In the crystal, N—H⋯I hydrogen bonds link the components into [100] chains.
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spelling pubmed-87391972022-01-24 Synthesis and crystal structure of (E)-2-benzyl-1,3-di­phenyl­iso­thio­uronium iodide Kang, Sungmin Kim, Taek Hyeon Kwak, Chee-Hun Acta Crystallogr E Crystallogr Commun Research Communications In the title mol­ecular salt, C(20)H(19)N(2)S(+)·I(−), prepared by the reaction of 1,3-di­phenyl­thio­urea and benzyl iodide, the C—S—C thio­ether bond angle is 101.66 (9)° and electrons are delocalized over the N(+)= C—N skeleton. The dihedral angle between the aromatic rings attached to the N atoms is 40.60 (9)°. In the crystal, N—H⋯I hydrogen bonds link the components into [100] chains. International Union of Crystallography 2022-01-01 /pmc/articles/PMC8739197/ /pubmed/35079424 http://dx.doi.org/10.1107/S2056989021013086 Text en © Kang et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Kang, Sungmin
Kim, Taek Hyeon
Kwak, Chee-Hun
Synthesis and crystal structure of (E)-2-benzyl-1,3-di­phenyl­iso­thio­uronium iodide
title Synthesis and crystal structure of (E)-2-benzyl-1,3-di­phenyl­iso­thio­uronium iodide
title_full Synthesis and crystal structure of (E)-2-benzyl-1,3-di­phenyl­iso­thio­uronium iodide
title_fullStr Synthesis and crystal structure of (E)-2-benzyl-1,3-di­phenyl­iso­thio­uronium iodide
title_full_unstemmed Synthesis and crystal structure of (E)-2-benzyl-1,3-di­phenyl­iso­thio­uronium iodide
title_short Synthesis and crystal structure of (E)-2-benzyl-1,3-di­phenyl­iso­thio­uronium iodide
title_sort synthesis and crystal structure of (e)-2-benzyl-1,3-di­phenyl­iso­thio­uronium iodide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8739197/
https://www.ncbi.nlm.nih.gov/pubmed/35079424
http://dx.doi.org/10.1107/S2056989021013086
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AT kwakcheehun synthesisandcrystalstructureofe2benzyl13diphenylisothiouroniumiodide

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