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Crystal structure and Hirshfeld surface analysis of 6,6′-((1E,1′E)-{[1,4-phenyl­enebis(methyl­ene)]bis(aza­nylyl­idene)}bis­(methane­ylyl­idene))bis­(2-meth­oxy­phenol)

The Schiff base compound, C(24)H(24)N(2)O(4), was synthesized by the inter­action of 2-hy­droxy-3-meth­oxy benzaldehyde and 1,4-benzene dimethanamine in ethanol, and crystallizes in the monoclinic space group P2(1)/n with Z′ = 0.5. The mol­ecule is not planar, the 1,4-di­ethyl­benzene and the phenol...

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Autores principales: Kansiz, Sevgi, Yesilbag, Semanur, Dege, Necmi, Saif, Eiad, Agar, Erbil
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8739199/
https://www.ncbi.nlm.nih.gov/pubmed/35079431
http://dx.doi.org/10.1107/S2056989021013347
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author Kansiz, Sevgi
Yesilbag, Semanur
Dege, Necmi
Saif, Eiad
Agar, Erbil
author_facet Kansiz, Sevgi
Yesilbag, Semanur
Dege, Necmi
Saif, Eiad
Agar, Erbil
author_sort Kansiz, Sevgi
collection PubMed
description The Schiff base compound, C(24)H(24)N(2)O(4), was synthesized by the inter­action of 2-hy­droxy-3-meth­oxy benzaldehyde and 1,4-benzene dimethanamine in ethanol, and crystallizes in the monoclinic space group P2(1)/n with Z′ = 0.5. The mol­ecule is not planar, the 1,4-di­ethyl­benzene and the phenol rings are twisted with respect to each other, making a dihedral angle of 74.27 (5)°. The mol­ecular structure is stabilized by an O—H⋯N hydrogen bond, forming an S(6) ring motif. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, resulting in the formation of sheets parallel to the bc plane. A Hirshfeld surface analysis was undertaken to investigate the various inter­molecular contacts controlling the supra­molecular topology, suggesting the H⋯O (18%) contacts to be the most significant inter­actions, whereas the H⋯H (50.5%) and C⋯H (24.3%) inter­actions are less significant.
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spelling pubmed-87391992022-01-24 Crystal structure and Hirshfeld surface analysis of 6,6′-((1E,1′E)-{[1,4-phenyl­enebis(methyl­ene)]bis(aza­nylyl­idene)}bis­(methane­ylyl­idene))bis­(2-meth­oxy­phenol) Kansiz, Sevgi Yesilbag, Semanur Dege, Necmi Saif, Eiad Agar, Erbil Acta Crystallogr E Crystallogr Commun Research Communications The Schiff base compound, C(24)H(24)N(2)O(4), was synthesized by the inter­action of 2-hy­droxy-3-meth­oxy benzaldehyde and 1,4-benzene dimethanamine in ethanol, and crystallizes in the monoclinic space group P2(1)/n with Z′ = 0.5. The mol­ecule is not planar, the 1,4-di­ethyl­benzene and the phenol rings are twisted with respect to each other, making a dihedral angle of 74.27 (5)°. The mol­ecular structure is stabilized by an O—H⋯N hydrogen bond, forming an S(6) ring motif. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, resulting in the formation of sheets parallel to the bc plane. A Hirshfeld surface analysis was undertaken to investigate the various inter­molecular contacts controlling the supra­molecular topology, suggesting the H⋯O (18%) contacts to be the most significant inter­actions, whereas the H⋯H (50.5%) and C⋯H (24.3%) inter­actions are less significant. International Union of Crystallography 2022-01-01 /pmc/articles/PMC8739199/ /pubmed/35079431 http://dx.doi.org/10.1107/S2056989021013347 Text en © Kansiz et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Kansiz, Sevgi
Yesilbag, Semanur
Dege, Necmi
Saif, Eiad
Agar, Erbil
Crystal structure and Hirshfeld surface analysis of 6,6′-((1E,1′E)-{[1,4-phenyl­enebis(methyl­ene)]bis(aza­nylyl­idene)}bis­(methane­ylyl­idene))bis­(2-meth­oxy­phenol)
title Crystal structure and Hirshfeld surface analysis of 6,6′-((1E,1′E)-{[1,4-phenyl­enebis(methyl­ene)]bis(aza­nylyl­idene)}bis­(methane­ylyl­idene))bis­(2-meth­oxy­phenol)
title_full Crystal structure and Hirshfeld surface analysis of 6,6′-((1E,1′E)-{[1,4-phenyl­enebis(methyl­ene)]bis(aza­nylyl­idene)}bis­(methane­ylyl­idene))bis­(2-meth­oxy­phenol)
title_fullStr Crystal structure and Hirshfeld surface analysis of 6,6′-((1E,1′E)-{[1,4-phenyl­enebis(methyl­ene)]bis(aza­nylyl­idene)}bis­(methane­ylyl­idene))bis­(2-meth­oxy­phenol)
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of 6,6′-((1E,1′E)-{[1,4-phenyl­enebis(methyl­ene)]bis(aza­nylyl­idene)}bis­(methane­ylyl­idene))bis­(2-meth­oxy­phenol)
title_short Crystal structure and Hirshfeld surface analysis of 6,6′-((1E,1′E)-{[1,4-phenyl­enebis(methyl­ene)]bis(aza­nylyl­idene)}bis­(methane­ylyl­idene))bis­(2-meth­oxy­phenol)
title_sort crystal structure and hirshfeld surface analysis of 6,6′-((1e,1′e)-{[1,4-phenyl­enebis(methyl­ene)]bis(aza­nylyl­idene)}bis­(methane­ylyl­idene))bis­(2-meth­oxy­phenol)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8739199/
https://www.ncbi.nlm.nih.gov/pubmed/35079431
http://dx.doi.org/10.1107/S2056989021013347
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