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Crystal structure of N,N,N′,N′-tetramethylethanediamine
The title compound N,N,N′,N′-tetramethylethanediamine, C(6)H(16)N(2), is a bidentate amine ligand commonly used in organolithium chemistry for deaggregation. Crystals were grown at 243 K from n-pentane solution. The complete molecule is generated by a crystallographic center of symmetry and the...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8739202/ https://www.ncbi.nlm.nih.gov/pubmed/35079420 http://dx.doi.org/10.1107/S2056989021012457 |
Sumario: | The title compound N,N,N′,N′-tetramethylethanediamine, C(6)H(16)N(2), is a bidentate amine ligand commonly used in organolithium chemistry for deaggregation. Crystals were grown at 243 K from n-pentane solution. The complete molecule is generated by a crystallographic center of symmetry and the conformation of the diamine is antiperiplanar. To investigate the intermolecular interactions, a Hirshfeld surface analysis was performed. It showed that H⋯H (van der Waals) interactions dominate with a contact percentage of 92.3%. |
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