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Crystal structure of N,N,N′,N′-tetra­methyl­ethane­di­amine

The title compound N,N,N′,N′-tetra­methyl­ethanedi­amine, C(6)H(16)N(2), is a bidentate amine ligand commonly used in organolithium chemistry for deaggregation. Crystals were grown at 243 K from n-pentane solution. The complete mol­ecule is generated by a crystallographic center of symmetry and the...

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Detalles Bibliográficos
Autores principales: Schrimpf, Tobias, Otte, Felix, Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8739202/
https://www.ncbi.nlm.nih.gov/pubmed/35079420
http://dx.doi.org/10.1107/S2056989021012457
Descripción
Sumario:The title compound N,N,N′,N′-tetra­methyl­ethanedi­amine, C(6)H(16)N(2), is a bidentate amine ligand commonly used in organolithium chemistry for deaggregation. Crystals were grown at 243 K from n-pentane solution. The complete mol­ecule is generated by a crystallographic center of symmetry and the conformation of the di­amine is anti­periplanar. To investigate the inter­molecular inter­actions, a Hirshfeld surface analysis was performed. It showed that H⋯H (van der Waals) inter­actions dominate with a contact percentage of 92.3%.