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Synthesis and structure of a new bulky bis­(alkoxide) ligand on a terphenyl platform

A new sterically bulky chelating bis­(alkoxide) ligand 3,3′-([1,1′:4′,1′′-terphen­yl]-2,2′′-di­yl)bis­(2,2,4,4-tetra­methyl­pentan-3-ol), (H(2)[OO](tBu)), was prepared in a two-step process as the di­chloro­methane monosolvate, C(36)H(50)O(2)·CH(2)Cl(2). The first step is a Suzuki–Miyaura coupling r...

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Detalles Bibliográficos
Autores principales: Kurup, Sudheer S., Nasser, Sandra, Ward, Cassandra L., Groysman, Stanislav
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8739204/
https://www.ncbi.nlm.nih.gov/pubmed/35079433
http://dx.doi.org/10.1107/S2056989021013438