Bis(η(5)-cyclo­penta­dien­yl)(2-{[(2-meth­oxy­phen­yl)imino]­meth­yl}phenolato-κ(3) O,N,O′)terbium

The air- and moisture-sensitive title compound, [Tb(C(5)H(5))(2)(C(14)H(12)NO(2))], was synthesized from tris­(cyclo­penta­dien­yl)(tetra­hydro­furan)­terbium and 2-{[(2-meth­oxy­phen­yl)imino]­meth­yl}phenol. Each Tb atom is coordinated by two cyclo­penta­dienyl ligands in an η(5)-coordination mode...

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Detalles Bibliográficos
Autores principales: Minyaev, Mikhail E., Lyssenko, Konstantin A., Roitershtein, Dmitrii M., Nifant’ev, Ilya E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8739212/
https://www.ncbi.nlm.nih.gov/pubmed/35079422
http://dx.doi.org/10.1107/S2056989021013025
Descripción
Sumario:The air- and moisture-sensitive title compound, [Tb(C(5)H(5))(2)(C(14)H(12)NO(2))], was synthesized from tris­(cyclo­penta­dien­yl)(tetra­hydro­furan)­terbium and 2-{[(2-meth­oxy­phen­yl)imino]­meth­yl}phenol. Each Tb atom is coordinated by two cyclo­penta­dienyl ligands in an η(5)-coordination mode and by one N and two O atoms of the organic ligand in a tridentate κ(3) O,N,O′-mode.

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