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Bis(η(5)-cyclopentadienyl)(2-{[(2-methoxyphenyl)imino]methyl}phenolato-κ(3) O,N,O′)terbium
The air- and moisture-sensitive title compound, [Tb(C(5)H(5))(2)(C(14)H(12)NO(2))], was synthesized from tris(cyclopentadienyl)(tetrahydrofuran)terbium and 2-{[(2-methoxyphenyl)imino]methyl}phenol. Each Tb atom is coordinated by two cyclopentadienyl ligands in an η(5)-coordination mode...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8739212/ https://www.ncbi.nlm.nih.gov/pubmed/35079422 http://dx.doi.org/10.1107/S2056989021013025 |
| _version_ | 1784629054539825152 |
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| author | Minyaev, Mikhail E. Lyssenko, Konstantin A. Roitershtein, Dmitrii M. Nifant’ev, Ilya E. |
| author_facet | Minyaev, Mikhail E. Lyssenko, Konstantin A. Roitershtein, Dmitrii M. Nifant’ev, Ilya E. |
| author_sort | Minyaev, Mikhail E. |
| collection | PubMed |
| description | The air- and moisture-sensitive title compound, [Tb(C(5)H(5))(2)(C(14)H(12)NO(2))], was synthesized from tris(cyclopentadienyl)(tetrahydrofuran)terbium and 2-{[(2-methoxyphenyl)imino]methyl}phenol. Each Tb atom is coordinated by two cyclopentadienyl ligands in an η(5)-coordination mode and by one N and two O atoms of the organic ligand in a tridentate κ(3) O,N,O′-mode. |
| format | Online Article Text |
| id | pubmed-8739212 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2022 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-87392122022-01-24 Bis(η(5)-cyclopentadienyl)(2-{[(2-methoxyphenyl)imino]methyl}phenolato-κ(3) O,N,O′)terbium Minyaev, Mikhail E. Lyssenko, Konstantin A. Roitershtein, Dmitrii M. Nifant’ev, Ilya E. Acta Crystallogr E Crystallogr Commun Research Communications The air- and moisture-sensitive title compound, [Tb(C(5)H(5))(2)(C(14)H(12)NO(2))], was synthesized from tris(cyclopentadienyl)(tetrahydrofuran)terbium and 2-{[(2-methoxyphenyl)imino]methyl}phenol. Each Tb atom is coordinated by two cyclopentadienyl ligands in an η(5)-coordination mode and by one N and two O atoms of the organic ligand in a tridentate κ(3) O,N,O′-mode. International Union of Crystallography 2022-01-01 /pmc/articles/PMC8739212/ /pubmed/35079422 http://dx.doi.org/10.1107/S2056989021013025 Text en © Minyaev et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Minyaev, Mikhail E. Lyssenko, Konstantin A. Roitershtein, Dmitrii M. Nifant’ev, Ilya E. Bis(η(5)-cyclopentadienyl)(2-{[(2-methoxyphenyl)imino]methyl}phenolato-κ(3) O,N,O′)terbium |
| title | Bis(η(5)-cyclopentadienyl)(2-{[(2-methoxyphenyl)imino]methyl}phenolato-κ(3)
O,N,O′)terbium |
| title_full | Bis(η(5)-cyclopentadienyl)(2-{[(2-methoxyphenyl)imino]methyl}phenolato-κ(3)
O,N,O′)terbium |
| title_fullStr | Bis(η(5)-cyclopentadienyl)(2-{[(2-methoxyphenyl)imino]methyl}phenolato-κ(3)
O,N,O′)terbium |
| title_full_unstemmed | Bis(η(5)-cyclopentadienyl)(2-{[(2-methoxyphenyl)imino]methyl}phenolato-κ(3)
O,N,O′)terbium |
| title_short | Bis(η(5)-cyclopentadienyl)(2-{[(2-methoxyphenyl)imino]methyl}phenolato-κ(3)
O,N,O′)terbium |
| title_sort | bis(η(5)-cyclopentadienyl)(2-{[(2-methoxyphenyl)imino]methyl}phenolato-κ(3)
o,n,o′)terbium |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8739212/ https://www.ncbi.nlm.nih.gov/pubmed/35079422 http://dx.doi.org/10.1107/S2056989021013025 |
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