Cargando…

On the Quantum Chemical Nature of Lead(II) “Lone Pair”

We study the quantum chemical nature of the Lead(II) valence basins, sometimes called the lead “lone pair”. Using various chemical interpretation tools, such as molecular orbital analysis, natural bond orbitals (NBO), natural population analysis (NPA) and electron localization function (ELF) topolog...

Descripción completa

Detalles Bibliográficos
Autores principales:	Gourlaouen, Christophe, Piquemal, Jean-Philip
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2021
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8746439/ https://www.ncbi.nlm.nih.gov/pubmed/35011259 http://dx.doi.org/10.3390/molecules27010027

Ejemplares similares

On the Significance of Lone Pair/Lone Pair and Lone Pair/Bond Pair Repulsions in the Cation Affinity and Lewis Acid/Lewis Base Interactions
por: Valadbeigi, Younes, et al.
Publicado: (2018)

Lone Pair Rotation and Bond Heterogeneity Leading to Ultralow Thermal Conductivity in Aikinite
por: Carnevali, Virginia, et al.
Publicado: (2023)

A Chemical-Pressure-Induced Phase Transition Controlled by Lone Electron Pair Activity
por: Gomes, Eduardo O., et al.
Publicado: (2022)

A lonely electron blocks incoming pairs
por: Massari, Marta, et al.
Publicado: (2021)

On the satisfaction of backbone‐carbonyl lone pairs of electrons in protein structures
por: Bartlett, Gail J., et al.
Publicado: (2016)

Thiophenylazobenzene: An Alternative Photoisomerization Controlled by Lone‐Pair⋅⋅⋅π Interaction
por: Slavov, Chavdar, et al.
Publicado: (2019)

Lone-Pair-Enabled Polymorphism and Photostructural Changes in Chalcogenide Glasses
por: Kolobov, Alexander V., et al.
Publicado: (2023)

Lonely
Publicado: (1888)

Structural Influence of Lone Pairs in GeP(2)N(4), a Germanium(II) Nitridophosphate
por: Ambach, Sebastian J., et al.
Publicado: (2022)

Dynamic Lone Pairs and Fluoride-Ion Disorder in Cubic-BaSnF(4)
por: Mercadier, Briséïs, et al.
Publicado: (2023)

Lone Atrial Flutter in Children and Adolescents: Is It Really “Lone”?
por: Dieks, Jana-K., et al.
Publicado: (2020)

Role of lone-pair electron localization in temperature-induced phase transitions in mimetite
por: Cametti, Georgia, et al.
Publicado: (2022)

Cospatial σ-Hole and Lone Pair Interactions of Square-Pyramidal Pentavalent Halogen Compounds with π-Systems: A Quantum Mechanical Study
por: Ibrahim, Mahmoud A. A., et al.
Publicado: (2021)

"The lone wagon"
por: CERN Bulletin
Publicado: (2012)

Risk Factors between Patients with Lone and Non-Lone Atrial Fibrillation
por: Lee, Sung Ho, et al.
Publicado: (2013)

Expression and interactions of stereochemically active lone pairs and their relation to structural distortions and thermal conductivity
por: Tolborg, Kasper, et al.
Publicado: (2020)

Lonely Points in Simplices
por: Jaroschek, Maximilian, et al.
Publicado: (2022)

Lonely places or lonely people? Investigating the relationship between loneliness and place of residence
por: Victor, Christina R., et al.
Publicado: (2020)

Pressure-Enhanced Photocurrent in One-Dimensional SbSI via Lone-Pair Electron Reconfiguration
por: Liu, Tianbiao, et al.
Publicado: (2022)

Alone, lonely, and missed
por: Kahn, James
Publicado: (2021)

Quantum-Chemistry Based Design of Halobenzene Derivatives With Augmented Affinities for the HIV-1 Viral G(4)/C(16) Base-Pair
por: El Darazi, Perla, et al.
Publicado: (2020)

Lonely minds in the universe
por: Genta, Giancarlo
Publicado: (2007)

Lonely Chairs at CERN
por: Gonzalez Suarez, Rebeca
Publicado: (2015)

Occurrence and stability of lone pair–π stacking interactions between ribose and nucleobases in functional RNAs
por: Chawla, Mohit, et al.
Publicado: (2017)

σ-Hole and Lone-Pair Hole Interactions in Chalcogen-Containing Complexes: A Comparative Study
por: Ibrahim, Mahmoud A. A., et al.
Publicado: (2020)

The effect of nitrogen lone-pair interaction on the conduction in a single-molecule junction with amine-Au bonding
por: Sugita, Yoshihiro, et al.
Publicado: (2018)

Crystal engineering of high explosives through lone pair-π interactions: Insights for improving thermal safety
por: Savastano, Matteo, et al.
Publicado: (2023)

Turn‐On Photocatalysis: Creating Lone‐Pair Donor–Acceptor Bonds in Organic Photosensitizer to Enhance Intersystem Crossing
por: Liu, Mingjie, et al.
Publicado: (2021)

Occurrence and stability of lone pair-π and OH–π interactions between water and nucleobases in functional RNAs
por: Kalra, Kanav, et al.
Publicado: (2020)

Efficient Lone-Pair-Driven Luminescence: Structure–Property Relationships in Emissive 5s(2) Metal Halides
por: McCall, Kyle M., et al.
Publicado: (2020)

Lonely receptors kill cells
por: LeBrasseur, Nicole
Publicado: (2003)

The heart is a lonely hunter /
por: McCullers, Carson, 1917-1967
Publicado: (2000)

The Lone Star Medical Association
Publicado: (1888)

Positive and negative experiences with the COVID-19 pandemic among lonely and non-lonely populations in Germany
por: Wegner, Luisa, et al.
Publicado: (2023)

Experimental and Theoretical Study of Ni(II)‐ and Pd(II)‐Promoted Double Geminal C(sp(3))−H Bond Activation Providing Facile Access to NHC Pincer Complexes: Isolated Intermediates and Mechanism
por: He, Fengkai, et al.
Publicado: (2022)

Lonely Alone or Lonely Together? A Cultural-Psychological Examination of Individualism–Collectivism and Loneliness in Five European Countries
por: Heu, Luzia C., et al.
Publicado: (2018)

Isolation of a Diylide‐Stabilized Stannylene and Germylene: Enhanced Donor Strength through Coplanar Lone Pair Alignment
por: Mohapatra, Chandrajeet, et al.
Publicado: (2019)

Modulation of the Bi(3+) 6s(2) Lone Pair State in Perovskites for High‐Mobility p‐Type Oxide Semiconductors
por: Shi, Jueli, et al.
Publicado: (2022)

Bromine Pentafluoride BrF(5), the Formation of [BrF(6)](−) Salts, and the Stereochemical (In)activity of the Bromine Lone Pairs
por: Möbs, Martin, et al.
Publicado: (2022)

Lonely Arginine Seeks Friendly Environment
por: Roux, Benoit
Publicado: (2007)

Cannot write session to /tmp/vufind_sessions/sess_ebk987647r5jpvi0ih95ihdskq