Experimental Investigations of AlMg3 Components with Polyurethane and Graphene Oxide Nanosheets Composite Coatings, after Accelerated UV-Aging

The use of graphene (Gr) and its derivates graphene oxide (GO) showed that these materials are good candidates to enhance the properties of polyurethane (PU) coatings, especially the anticorrosion ones since graphene absorbs most of the light and provides hydrophobicity for repelling water. An important aspect of these multifunctional materials is that all these improvements can be realized even at very low filler loadings in the polymer matrix. In this work, an ultrasound cavitation technique was used for the proper dispersion of GO nanosheets (GON) in polyurethane (PU) resin to obtain a composite coating to protect the AlMg3 substrate. The addition of GON considerably improved the physical properties of coatings, as demonstrated by electrochemical impedance spectroscopy (EIS) analysis, promising improved anticorrosion performance after accelerated UV-ageing. Computational methods and Differential Scanning Calorimetry (DSC) measurements showed that GON facilitates the formation of additional bonds and stabilizes the PU structures during the ultraviolet (UV) exposure and aggressive attack of corrosive species. Limiting oxygen index (LOI) data reveal a slow burning behaviour of PU-GON coatings during UV exposure, which is better than PU alone.