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Expanded Beads of High Melt Strength Polypropylene Moldable at Low Steam Pressure by Foam Extrusion

We explore the foam extrusion of expanded polypropylene with a long chain branched random co-polypropylene to make its production process simpler and cheaper. The results show that the presence of long chain branches infer high melt strength and, hence, a wide foamability window. We explored the ent...

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Autores principales: Tammaro, Daniele, Ballesteros, Alberto, Walker, Claudio, Reichelt, Norbert, Trommsdorff, Ulla
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8747224/
https://www.ncbi.nlm.nih.gov/pubmed/35012225
http://dx.doi.org/10.3390/polym14010205
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author Tammaro, Daniele
Ballesteros, Alberto
Walker, Claudio
Reichelt, Norbert
Trommsdorff, Ulla
author_facet Tammaro, Daniele
Ballesteros, Alberto
Walker, Claudio
Reichelt, Norbert
Trommsdorff, Ulla
author_sort Tammaro, Daniele
collection PubMed
description We explore the foam extrusion of expanded polypropylene with a long chain branched random co-polypropylene to make its production process simpler and cheaper. The results show that the presence of long chain branches infer high melt strength and, hence, a wide foamability window. We explored the entire window of foaming conditions (namely, temperature and pressure) by means of an ad-hoc extrusion pilot line design. It is shown that the density of the beads can be varied from 20 to 100 kg/m(3) using CO(2) and isobutane as a blowing agent. The foamed beads were molded by steam-chest molding using moderate steam pressures of 0.3 to 0.35 MPa independently of the closed cell content. A characterization of the mechanical properties was performed on the molded parts. The steam molding pressure for sintering expanded polypropylene beads with a long chain branched random co-polypropylene is lower than the one usually needed for standard polypropylene beads by extrusion. The energy saving for the sintering makes the entire manufacturing processes cost efficient and can trigger new applications.
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spelling pubmed-87472242022-01-11 Expanded Beads of High Melt Strength Polypropylene Moldable at Low Steam Pressure by Foam Extrusion Tammaro, Daniele Ballesteros, Alberto Walker, Claudio Reichelt, Norbert Trommsdorff, Ulla Polymers (Basel) Article We explore the foam extrusion of expanded polypropylene with a long chain branched random co-polypropylene to make its production process simpler and cheaper. The results show that the presence of long chain branches infer high melt strength and, hence, a wide foamability window. We explored the entire window of foaming conditions (namely, temperature and pressure) by means of an ad-hoc extrusion pilot line design. It is shown that the density of the beads can be varied from 20 to 100 kg/m(3) using CO(2) and isobutane as a blowing agent. The foamed beads were molded by steam-chest molding using moderate steam pressures of 0.3 to 0.35 MPa independently of the closed cell content. A characterization of the mechanical properties was performed on the molded parts. The steam molding pressure for sintering expanded polypropylene beads with a long chain branched random co-polypropylene is lower than the one usually needed for standard polypropylene beads by extrusion. The energy saving for the sintering makes the entire manufacturing processes cost efficient and can trigger new applications. MDPI 2022-01-05 /pmc/articles/PMC8747224/ /pubmed/35012225 http://dx.doi.org/10.3390/polym14010205 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Tammaro, Daniele
Ballesteros, Alberto
Walker, Claudio
Reichelt, Norbert
Trommsdorff, Ulla
Expanded Beads of High Melt Strength Polypropylene Moldable at Low Steam Pressure by Foam Extrusion
title Expanded Beads of High Melt Strength Polypropylene Moldable at Low Steam Pressure by Foam Extrusion
title_full Expanded Beads of High Melt Strength Polypropylene Moldable at Low Steam Pressure by Foam Extrusion
title_fullStr Expanded Beads of High Melt Strength Polypropylene Moldable at Low Steam Pressure by Foam Extrusion
title_full_unstemmed Expanded Beads of High Melt Strength Polypropylene Moldable at Low Steam Pressure by Foam Extrusion
title_short Expanded Beads of High Melt Strength Polypropylene Moldable at Low Steam Pressure by Foam Extrusion
title_sort expanded beads of high melt strength polypropylene moldable at low steam pressure by foam extrusion
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8747224/
https://www.ncbi.nlm.nih.gov/pubmed/35012225
http://dx.doi.org/10.3390/polym14010205
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