Cargando…
Expanded Beads of High Melt Strength Polypropylene Moldable at Low Steam Pressure by Foam Extrusion
We explore the foam extrusion of expanded polypropylene with a long chain branched random co-polypropylene to make its production process simpler and cheaper. The results show that the presence of long chain branches infer high melt strength and, hence, a wide foamability window. We explored the ent...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8747224/ https://www.ncbi.nlm.nih.gov/pubmed/35012225 http://dx.doi.org/10.3390/polym14010205 |
_version_ | 1784630781589585920 |
---|---|
author | Tammaro, Daniele Ballesteros, Alberto Walker, Claudio Reichelt, Norbert Trommsdorff, Ulla |
author_facet | Tammaro, Daniele Ballesteros, Alberto Walker, Claudio Reichelt, Norbert Trommsdorff, Ulla |
author_sort | Tammaro, Daniele |
collection | PubMed |
description | We explore the foam extrusion of expanded polypropylene with a long chain branched random co-polypropylene to make its production process simpler and cheaper. The results show that the presence of long chain branches infer high melt strength and, hence, a wide foamability window. We explored the entire window of foaming conditions (namely, temperature and pressure) by means of an ad-hoc extrusion pilot line design. It is shown that the density of the beads can be varied from 20 to 100 kg/m(3) using CO(2) and isobutane as a blowing agent. The foamed beads were molded by steam-chest molding using moderate steam pressures of 0.3 to 0.35 MPa independently of the closed cell content. A characterization of the mechanical properties was performed on the molded parts. The steam molding pressure for sintering expanded polypropylene beads with a long chain branched random co-polypropylene is lower than the one usually needed for standard polypropylene beads by extrusion. The energy saving for the sintering makes the entire manufacturing processes cost efficient and can trigger new applications. |
format | Online Article Text |
id | pubmed-8747224 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-87472242022-01-11 Expanded Beads of High Melt Strength Polypropylene Moldable at Low Steam Pressure by Foam Extrusion Tammaro, Daniele Ballesteros, Alberto Walker, Claudio Reichelt, Norbert Trommsdorff, Ulla Polymers (Basel) Article We explore the foam extrusion of expanded polypropylene with a long chain branched random co-polypropylene to make its production process simpler and cheaper. The results show that the presence of long chain branches infer high melt strength and, hence, a wide foamability window. We explored the entire window of foaming conditions (namely, temperature and pressure) by means of an ad-hoc extrusion pilot line design. It is shown that the density of the beads can be varied from 20 to 100 kg/m(3) using CO(2) and isobutane as a blowing agent. The foamed beads were molded by steam-chest molding using moderate steam pressures of 0.3 to 0.35 MPa independently of the closed cell content. A characterization of the mechanical properties was performed on the molded parts. The steam molding pressure for sintering expanded polypropylene beads with a long chain branched random co-polypropylene is lower than the one usually needed for standard polypropylene beads by extrusion. The energy saving for the sintering makes the entire manufacturing processes cost efficient and can trigger new applications. MDPI 2022-01-05 /pmc/articles/PMC8747224/ /pubmed/35012225 http://dx.doi.org/10.3390/polym14010205 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Tammaro, Daniele Ballesteros, Alberto Walker, Claudio Reichelt, Norbert Trommsdorff, Ulla Expanded Beads of High Melt Strength Polypropylene Moldable at Low Steam Pressure by Foam Extrusion |
title | Expanded Beads of High Melt Strength Polypropylene Moldable at Low Steam Pressure by Foam Extrusion |
title_full | Expanded Beads of High Melt Strength Polypropylene Moldable at Low Steam Pressure by Foam Extrusion |
title_fullStr | Expanded Beads of High Melt Strength Polypropylene Moldable at Low Steam Pressure by Foam Extrusion |
title_full_unstemmed | Expanded Beads of High Melt Strength Polypropylene Moldable at Low Steam Pressure by Foam Extrusion |
title_short | Expanded Beads of High Melt Strength Polypropylene Moldable at Low Steam Pressure by Foam Extrusion |
title_sort | expanded beads of high melt strength polypropylene moldable at low steam pressure by foam extrusion |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8747224/ https://www.ncbi.nlm.nih.gov/pubmed/35012225 http://dx.doi.org/10.3390/polym14010205 |
work_keys_str_mv | AT tammarodaniele expandedbeadsofhighmeltstrengthpolypropylenemoldableatlowsteampressurebyfoamextrusion AT ballesterosalberto expandedbeadsofhighmeltstrengthpolypropylenemoldableatlowsteampressurebyfoamextrusion AT walkerclaudio expandedbeadsofhighmeltstrengthpolypropylenemoldableatlowsteampressurebyfoamextrusion AT reicheltnorbert expandedbeadsofhighmeltstrengthpolypropylenemoldableatlowsteampressurebyfoamextrusion AT trommsdorffulla expandedbeadsofhighmeltstrengthpolypropylenemoldableatlowsteampressurebyfoamextrusion |