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Stability Efficiencies of POSS and Microalgae Extracts on the Durability of Ethylene-Propylene-Diene Monomer Based Hybrids

The EPDM (ethylene-propylene-diene monomer) hybrids with improved thermal and radiation strengths containing 1 and 5 phr of polyhedral oligomeric silsesquioxane (vinyl-POSS, Ov-POSS) and/or 2 phr of microalgae (Chlorella vulgaris (CV) and Spirulina platensis (SP)) powders were investigated in respec...

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Autores principales: Zaharescu, Traian, Mateescu, Carmen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8747662/
https://www.ncbi.nlm.nih.gov/pubmed/35012209
http://dx.doi.org/10.3390/polym14010187
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author Zaharescu, Traian
Mateescu, Carmen
author_facet Zaharescu, Traian
Mateescu, Carmen
author_sort Zaharescu, Traian
collection PubMed
description The EPDM (ethylene-propylene-diene monomer) hybrids with improved thermal and radiation strengths containing 1 and 5 phr of polyhedral oligomeric silsesquioxane (vinyl-POSS, Ov-POSS) and/or 2 phr of microalgae (Chlorella vulgaris (CV) and Spirulina platensis (SP)) powders were investigated in respect to their thermal stability after γ-irradiation. The material durability under accelerated degradation was qualified by chemiluminescence and gelation, which prove the contribution of inorganic filler and microalgae extracts on the increase of hybrid thermal stability, as well as the interaction between added components (POSS and CV or SP). The activation energies and the durabilities under accelerated degradation were calculated, indicating their suitable usage as appropriate materials in various applications. The reported results indicate the improvement effect of both microalgal powders on the oxidation strength, but the contribution of Spirulina platensis grabs attention on its efficient effects upon the prevention of degradation under accelerated aging conditions. The thermal performances of the tested EPDM based hybrids are remarkably ameliorated, if the certain formulation includes Ov-POSS (5 phr) and Spirulina platensis (2 phr), certifying its suitability for the pertinent applications.
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spelling pubmed-87476622022-01-11 Stability Efficiencies of POSS and Microalgae Extracts on the Durability of Ethylene-Propylene-Diene Monomer Based Hybrids Zaharescu, Traian Mateescu, Carmen Polymers (Basel) Article The EPDM (ethylene-propylene-diene monomer) hybrids with improved thermal and radiation strengths containing 1 and 5 phr of polyhedral oligomeric silsesquioxane (vinyl-POSS, Ov-POSS) and/or 2 phr of microalgae (Chlorella vulgaris (CV) and Spirulina platensis (SP)) powders were investigated in respect to their thermal stability after γ-irradiation. The material durability under accelerated degradation was qualified by chemiluminescence and gelation, which prove the contribution of inorganic filler and microalgae extracts on the increase of hybrid thermal stability, as well as the interaction between added components (POSS and CV or SP). The activation energies and the durabilities under accelerated degradation were calculated, indicating their suitable usage as appropriate materials in various applications. The reported results indicate the improvement effect of both microalgal powders on the oxidation strength, but the contribution of Spirulina platensis grabs attention on its efficient effects upon the prevention of degradation under accelerated aging conditions. The thermal performances of the tested EPDM based hybrids are remarkably ameliorated, if the certain formulation includes Ov-POSS (5 phr) and Spirulina platensis (2 phr), certifying its suitability for the pertinent applications. MDPI 2022-01-03 /pmc/articles/PMC8747662/ /pubmed/35012209 http://dx.doi.org/10.3390/polym14010187 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zaharescu, Traian
Mateescu, Carmen
Stability Efficiencies of POSS and Microalgae Extracts on the Durability of Ethylene-Propylene-Diene Monomer Based Hybrids
title Stability Efficiencies of POSS and Microalgae Extracts on the Durability of Ethylene-Propylene-Diene Monomer Based Hybrids
title_full Stability Efficiencies of POSS and Microalgae Extracts on the Durability of Ethylene-Propylene-Diene Monomer Based Hybrids
title_fullStr Stability Efficiencies of POSS and Microalgae Extracts on the Durability of Ethylene-Propylene-Diene Monomer Based Hybrids
title_full_unstemmed Stability Efficiencies of POSS and Microalgae Extracts on the Durability of Ethylene-Propylene-Diene Monomer Based Hybrids
title_short Stability Efficiencies of POSS and Microalgae Extracts on the Durability of Ethylene-Propylene-Diene Monomer Based Hybrids
title_sort stability efficiencies of poss and microalgae extracts on the durability of ethylene-propylene-diene monomer based hybrids
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8747662/
https://www.ncbi.nlm.nih.gov/pubmed/35012209
http://dx.doi.org/10.3390/polym14010187
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