N=N Bond Cleavage by Tantalum Hydride Complexes: Mechanistic Insights and Reactivity

[Image: see text] The reaction of [TaCp(R)X(4)] (Cp(R) = η(5)-C(5)Me(5), η(5)-C(5)H(4)SiMe(3), η(5)-C(5)HMe(4); X = Cl, Br) with SiH(3)Ph resulted in the formation of the dinuclear hydride tantalum(IV) compounds [(TaCp(R)X(2))(2)(μ-H)(2)], structurally identified by single-crystal X-ray analyses. Th...

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Detalles Bibliográficos
Autores principales: Álvarez-Ruiz, Elena, Carbó, Jorge J., Gómez, Manuel, Hernández-Prieto, Cristina, Hernán-Gómez, Alberto, Martín, Avelino, Mena, Miguel, Ricart, Josep M., Salom-Català, Antoni, Santamaría, Cristina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8753601/
https://www.ncbi.nlm.nih.gov/pubmed/34890181
http://dx.doi.org/10.1021/acs.inorgchem.1c03152

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8753601/
https://www.ncbi.nlm.nih.gov/pubmed/34890181
http://dx.doi.org/10.1021/acs.inorgchem.1c03152

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