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N=N Bond Cleavage by Tantalum Hydride Complexes: Mechanistic Insights and Reactivity
[Image: see text] The reaction of [TaCp(R)X(4)] (Cp(R) = η(5)-C(5)Me(5), η(5)-C(5)H(4)SiMe(3), η(5)-C(5)HMe(4); X = Cl, Br) with SiH(3)Ph resulted in the formation of the dinuclear hydride tantalum(IV) compounds [(TaCp(R)X(2))(2)(μ-H)(2)], structurally identified by single-crystal X-ray analyses. Th...
Autores principales: | Álvarez-Ruiz, Elena, Carbó, Jorge J., Gómez, Manuel, Hernández-Prieto, Cristina, Hernán-Gómez, Alberto, Martín, Avelino, Mena, Miguel, Ricart, Josep M., Salom-Català, Antoni, Santamaría, Cristina |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8753601/ https://www.ncbi.nlm.nih.gov/pubmed/34890181 http://dx.doi.org/10.1021/acs.inorgchem.1c03152 |
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