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Synthesis and characterization of polymerizable MOFs for the preparation of MOF/polymer mixed matrix membranes
Mixed-matrix membranes (MMMs) comprising polymer matrices and metal-organic frameworks (MOFs) provide efficient and economic CO(2) separation. One major challenge is to construct continuous and defect-free MMMs due to poor MOF/polymer compatibility. Here, this protocol describes the step-by-step det...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8755569/ https://www.ncbi.nlm.nih.gov/pubmed/35059652 http://dx.doi.org/10.1016/j.xpro.2021.101039 |
Sumario: | Mixed-matrix membranes (MMMs) comprising polymer matrices and metal-organic frameworks (MOFs) provide efficient and economic CO(2) separation. One major challenge is to construct continuous and defect-free MMMs due to poor MOF/polymer compatibility. Here, this protocol describes the step-by-step details for synthesis of desired linkers that allow the fabrication of new polymerizable MOFs containing vinyl groups (BUCT MOFs) and the preparation procedures of defect-free MMMs with enhanced MOF/polymer interfacial adhesion and boosted gas separation performances. For complete details on the use and execution of this profile, please refer to Chen et al. (2021). |
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