Novel Clarification of Surface Plasmon Coupling Reactions of Aromatic Alkynamine and Nitro Compounds

[Image: see text] This work presents a theoretical and experimental approach for the coupling of 4-ethynylaniline (4-APA) and 4-ethynylnitrobenzene (4-NPA) in the theoretical application of density functional theory (DFT) and experimental monitoring of surface-enhanced Raman spectroscopy (SERS). The...

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Autores principales: Yang, Yanqiu, Luo, Jibiao, Song, Peng, Ding, Yong, Xia, Lixin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8756794/
https://www.ncbi.nlm.nih.gov/pubmed/35036779
http://dx.doi.org/10.1021/acsomega.1c05746
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author Yang, Yanqiu
Luo, Jibiao
Song, Peng
Ding, Yong
Xia, Lixin
author_facet Yang, Yanqiu
Luo, Jibiao
Song, Peng
Ding, Yong
Xia, Lixin
author_sort Yang, Yanqiu
collection PubMed
description [Image: see text] This work presents a theoretical and experimental approach for the coupling of 4-ethynylaniline (4-APA) and 4-ethynylnitrobenzene (4-NPA) in the theoretical application of density functional theory (DFT) and experimental monitoring of surface-enhanced Raman spectroscopy (SERS). The results support electromagnetic enhancement to drive the conversion of aromatic alkynamine and nitro compounds and regulation by the catalytic coupling reaction conditions. In addition, this work investigates the adsorption site effect of surface plasmon coupling reactions of 4-APA and 4-NPA molecules into alkynyl azo compounds. This study presents theoretical and experimental images used to analyze the plasmon-driven surface catalytic reaction system.
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spelling pubmed-87567942022-01-13 Novel Clarification of Surface Plasmon Coupling Reactions of Aromatic Alkynamine and Nitro Compounds Yang, Yanqiu Luo, Jibiao Song, Peng Ding, Yong Xia, Lixin ACS Omega [Image: see text] This work presents a theoretical and experimental approach for the coupling of 4-ethynylaniline (4-APA) and 4-ethynylnitrobenzene (4-NPA) in the theoretical application of density functional theory (DFT) and experimental monitoring of surface-enhanced Raman spectroscopy (SERS). The results support electromagnetic enhancement to drive the conversion of aromatic alkynamine and nitro compounds and regulation by the catalytic coupling reaction conditions. In addition, this work investigates the adsorption site effect of surface plasmon coupling reactions of 4-APA and 4-NPA molecules into alkynyl azo compounds. This study presents theoretical and experimental images used to analyze the plasmon-driven surface catalytic reaction system. American Chemical Society 2021-12-21 /pmc/articles/PMC8756794/ /pubmed/35036779 http://dx.doi.org/10.1021/acsomega.1c05746 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Yang, Yanqiu
Luo, Jibiao
Song, Peng
Ding, Yong
Xia, Lixin
Novel Clarification of Surface Plasmon Coupling Reactions of Aromatic Alkynamine and Nitro Compounds
title Novel Clarification of Surface Plasmon Coupling Reactions of Aromatic Alkynamine and Nitro Compounds
title_full Novel Clarification of Surface Plasmon Coupling Reactions of Aromatic Alkynamine and Nitro Compounds
title_fullStr Novel Clarification of Surface Plasmon Coupling Reactions of Aromatic Alkynamine and Nitro Compounds
title_full_unstemmed Novel Clarification of Surface Plasmon Coupling Reactions of Aromatic Alkynamine and Nitro Compounds
title_short Novel Clarification of Surface Plasmon Coupling Reactions of Aromatic Alkynamine and Nitro Compounds
title_sort novel clarification of surface plasmon coupling reactions of aromatic alkynamine and nitro compounds
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8756794/
https://www.ncbi.nlm.nih.gov/pubmed/35036779
http://dx.doi.org/10.1021/acsomega.1c05746
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AT dingyong novelclarificationofsurfaceplasmoncouplingreactionsofaromaticalkynamineandnitrocompounds
AT xialixin novelclarificationofsurfaceplasmoncouplingreactionsofaromaticalkynamineandnitrocompounds

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