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Nature of the Ligand-Centered Triplet State in Gd(3+) β-Diketonate Complexes as Revealed by Time-Resolved EPR Spectroscopy and DFT Calculations

[Image: see text] A series of Gd(3+) complexes (Gd1–Gd3) with the general formula GdL(3)(EtOH)(2), where L is a β-diketone ligand with polycyclic aromatic hydrocarbon substituents of increasing size (1–3), was studied by combining time-resolved electron paramagnetic resonance (TR-EPR) spectroscopy a...

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Detalles Bibliográficos
Autores principales:	Carlotto, Silvia, Babetto, Luca, Bortolus, Marco, Carlotto, Alice, Rancan, Marzio, Bottaro, Gregorio, Armelao, Lidia, Carbonera, Donatella, Casarin, Maurizio
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8763374/ https://www.ncbi.nlm.nih.gov/pubmed/34612628 http://dx.doi.org/10.1021/acs.inorgchem.1c01123

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