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Study on Oxygen Evolution Reaction Performance of Jarosite/C Composites
In the electrolysis of water process, hydrogen is produced and the anodic oxygen evolution reaction (OER) dominates the reaction rate of the entire process. Currently, OER catalysts mostly consist of noble metal (NM) catalysts, which cannot be applied in industries due to the high price. It is of gr...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8778213/ https://www.ncbi.nlm.nih.gov/pubmed/35057385 http://dx.doi.org/10.3390/ma15020668 |
Sumario: | In the electrolysis of water process, hydrogen is produced and the anodic oxygen evolution reaction (OER) dominates the reaction rate of the entire process. Currently, OER catalysts mostly consist of noble metal (NM) catalysts, which cannot be applied in industries due to the high price. It is of great importance to developing low-cost catalysts materials as NM materials substitution. In this work, jarosite (AFe(3)(SO(4))(2)(OH)(6), A = K(+), Na(+), NH(4+), H(3)O(+)) was synthesized by a one-step method, and its OER catalytic performance was studied using catalytic slurry (the weight ratios of jarosite and conductive carbon black are 2:1, 1:1 and 1:2). Microstructures and functional groups of synthesized material were analyzed using XRD, SEM, FI-IR, etc. The OER catalytic performance of (NH(4))Fe(3)(SO(4))(2)(OH)(6)/conductive carbon black were examined by LSV, Tafel, EIS, ECSA, etc. The study found that the OER has the best catalytic performance when the weight ratio of (NH(4))Fe(3)(SO(4))(2)(OH)(6) to conductive carbon black is 2:1. It requires only 376 mV overpotential to generate current densities of 10 mA cm(−2) with a small Tafel slope (82.42 mV dec(−1)) and large C(dl) value (26.17 mF cm(−2)). |
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