Facile Multiple Alkylations of C(60) Fullerene

The reduction of fullerene (C(60)) with sodium dispersion in the presence of an excess amount of dipropyl sulfate was found to yield highly propylated fullerene, C(60)(nC(3)H(7))(n) (max. n = 24), and C(60)(nC(3)H(7))(20) was predominantly generated as determined by mass spectroscopy.

Detalles Bibliográficos
Autores principales: Miwa, Kazuhira, Aoyagi, Shinobu, Sasamori, Takahiro, Morisako, Shogo, Ueno, Hiroshi, Matsuo, Yutaka, Yorimitsu, Hideki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8779915/
https://www.ncbi.nlm.nih.gov/pubmed/35056764
http://dx.doi.org/10.3390/molecules27020450
_version_ 1784637695336644608
author Miwa, Kazuhira
Aoyagi, Shinobu
Sasamori, Takahiro
Morisako, Shogo
Ueno, Hiroshi
Matsuo, Yutaka
Yorimitsu, Hideki
author_facet Miwa, Kazuhira
Aoyagi, Shinobu
Sasamori, Takahiro
Morisako, Shogo
Ueno, Hiroshi
Matsuo, Yutaka
Yorimitsu, Hideki
author_sort Miwa, Kazuhira
collection PubMed
description The reduction of fullerene (C(60)) with sodium dispersion in the presence of an excess amount of dipropyl sulfate was found to yield highly propylated fullerene, C(60)(nC(3)H(7))(n) (max. n = 24), and C(60)(nC(3)H(7))(20) was predominantly generated as determined by mass spectroscopy.
format Online
Article
Text
id pubmed-8779915
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-87799152022-01-22 Facile Multiple Alkylations of C(60) Fullerene Miwa, Kazuhira Aoyagi, Shinobu Sasamori, Takahiro Morisako, Shogo Ueno, Hiroshi Matsuo, Yutaka Yorimitsu, Hideki Molecules Article The reduction of fullerene (C(60)) with sodium dispersion in the presence of an excess amount of dipropyl sulfate was found to yield highly propylated fullerene, C(60)(nC(3)H(7))(n) (max. n = 24), and C(60)(nC(3)H(7))(20) was predominantly generated as determined by mass spectroscopy. MDPI 2022-01-10 /pmc/articles/PMC8779915/ /pubmed/35056764 http://dx.doi.org/10.3390/molecules27020450 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Miwa, Kazuhira
Aoyagi, Shinobu
Sasamori, Takahiro
Morisako, Shogo
Ueno, Hiroshi
Matsuo, Yutaka
Yorimitsu, Hideki
Facile Multiple Alkylations of C(60) Fullerene
title Facile Multiple Alkylations of C(60) Fullerene
title_full Facile Multiple Alkylations of C(60) Fullerene
title_fullStr Facile Multiple Alkylations of C(60) Fullerene
title_full_unstemmed Facile Multiple Alkylations of C(60) Fullerene
title_short Facile Multiple Alkylations of C(60) Fullerene
title_sort facile multiple alkylations of c(60) fullerene
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8779915/
https://www.ncbi.nlm.nih.gov/pubmed/35056764
http://dx.doi.org/10.3390/molecules27020450
work_keys_str_mv AT miwakazuhira facilemultiplealkylationsofc60fullerene
AT aoyagishinobu facilemultiplealkylationsofc60fullerene
AT sasamoritakahiro facilemultiplealkylationsofc60fullerene
AT morisakoshogo facilemultiplealkylationsofc60fullerene
AT uenohiroshi facilemultiplealkylationsofc60fullerene
AT matsuoyutaka facilemultiplealkylationsofc60fullerene
AT yorimitsuhideki facilemultiplealkylationsofc60fullerene

Ejemplares similares