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Anti-Electrostatic Pi-Hole Bonding: How Covalency Conquers Coulombics
Intermolecular bonding attraction at π-bonded centers is often described as “electrostatically driven” and given quasi-classical rationalization in terms of a “pi hole” depletion region in the electrostatic potential. However, we demonstrate here that such bonding attraction also occurs between clos...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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MDPI
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8780338/ https://www.ncbi.nlm.nih.gov/pubmed/35056689 http://dx.doi.org/10.3390/molecules27020377 |