Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for β-Alkylation of Secondary Alcohols with Primary Alcohols

Solid supports functionalized with molecular metal catalysts combine many of the advantages of heterogeneous and homogeneous catalysis. A (NNN)Ru-incorporated porous organic polymer (POP-bp/bbpRuCl(3)) exhibited high catalytic efficiency and broad functional group tolerance in the C–C cross-coupling...

Descripción completa

Detalles Bibliográficos
Autores principales: Cui, Yao, Wang, Jixian, Yu, Lei, Xu, Ying, Young, David J., Li, Haiyan, Li, Hongxi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8780954/
https://www.ncbi.nlm.nih.gov/pubmed/35054638
http://dx.doi.org/10.3390/polym14020231
_version_ 1784637969672437760
author Cui, Yao
Wang, Jixian
Yu, Lei
Xu, Ying
Young, David J.
Li, Haiyan
Li, Hongxi
author_facet Cui, Yao
Wang, Jixian
Yu, Lei
Xu, Ying
Young, David J.
Li, Haiyan
Li, Hongxi
author_sort Cui, Yao
collection PubMed
description Solid supports functionalized with molecular metal catalysts combine many of the advantages of heterogeneous and homogeneous catalysis. A (NNN)Ru-incorporated porous organic polymer (POP-bp/bbpRuCl(3)) exhibited high catalytic efficiency and broad functional group tolerance in the C–C cross-coupling of secondary and primary alcohols to give β-alkylated secondary alcohols. This catalyst demonstrated excellent durability during successive recycling without leaching of Ru which is ascribed to the strong binding of the pincer ligands to the metal ions.
format Online
Article
Text
id pubmed-8780954
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-87809542022-01-22 Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for β-Alkylation of Secondary Alcohols with Primary Alcohols Cui, Yao Wang, Jixian Yu, Lei Xu, Ying Young, David J. Li, Haiyan Li, Hongxi Polymers (Basel) Article Solid supports functionalized with molecular metal catalysts combine many of the advantages of heterogeneous and homogeneous catalysis. A (NNN)Ru-incorporated porous organic polymer (POP-bp/bbpRuCl(3)) exhibited high catalytic efficiency and broad functional group tolerance in the C–C cross-coupling of secondary and primary alcohols to give β-alkylated secondary alcohols. This catalyst demonstrated excellent durability during successive recycling without leaching of Ru which is ascribed to the strong binding of the pincer ligands to the metal ions. MDPI 2022-01-07 /pmc/articles/PMC8780954/ /pubmed/35054638 http://dx.doi.org/10.3390/polym14020231 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Cui, Yao
Wang, Jixian
Yu, Lei
Xu, Ying
Young, David J.
Li, Haiyan
Li, Hongxi
Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for β-Alkylation of Secondary Alcohols with Primary Alcohols
title Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for β-Alkylation of Secondary Alcohols with Primary Alcohols
title_full Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for β-Alkylation of Secondary Alcohols with Primary Alcohols
title_fullStr Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for β-Alkylation of Secondary Alcohols with Primary Alcohols
title_full_unstemmed Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for β-Alkylation of Secondary Alcohols with Primary Alcohols
title_short Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for β-Alkylation of Secondary Alcohols with Primary Alcohols
title_sort construction of a (nnn)ru-incorporated porous organic polymer with high catalytic activity for β-alkylation of secondary alcohols with primary alcohols
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8780954/
https://www.ncbi.nlm.nih.gov/pubmed/35054638
http://dx.doi.org/10.3390/polym14020231
work_keys_str_mv AT cuiyao constructionofannnruincorporatedporousorganicpolymerwithhighcatalyticactivityforbalkylationofsecondaryalcoholswithprimaryalcohols
AT wangjixian constructionofannnruincorporatedporousorganicpolymerwithhighcatalyticactivityforbalkylationofsecondaryalcoholswithprimaryalcohols
AT yulei constructionofannnruincorporatedporousorganicpolymerwithhighcatalyticactivityforbalkylationofsecondaryalcoholswithprimaryalcohols
AT xuying constructionofannnruincorporatedporousorganicpolymerwithhighcatalyticactivityforbalkylationofsecondaryalcoholswithprimaryalcohols
AT youngdavidj constructionofannnruincorporatedporousorganicpolymerwithhighcatalyticactivityforbalkylationofsecondaryalcoholswithprimaryalcohols
AT lihaiyan constructionofannnruincorporatedporousorganicpolymerwithhighcatalyticactivityforbalkylationofsecondaryalcoholswithprimaryalcohols
AT lihongxi constructionofannnruincorporatedporousorganicpolymerwithhighcatalyticactivityforbalkylationofsecondaryalcoholswithprimaryalcohols

Ejemplares similares