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Heterospin frustration in a metal-fullerene-bonded semiconductive antiferromagnet
Lithium-ion-encapsulated fullerenes (Li(+)@C(60)) are 3D superatoms with rich oxidative states. Here we show a conductive and magnetically frustrated metal–fullerene-bonded framework {[Cu(4)(Li@C(60))(L)(py)(4)](NTf(2))(hexane)}(n) (1) (L = 1,2,4,5-tetrakis(methanesulfonamido)benzene, py = pyridine,...
Autores principales: | Shen, Yongbing, Cui, Mengxing, Takaishi, Shinya, Kawasoko, Hideyuki, Sugimoto, Kunihisa, Tsumuraya, Takao, Otsuka, Akihiro, Kwon, Eunsang, Yoshida, Takefumi, Hoshino, Norihisa, Kawachi, Kazuhiko, Kasama, Yasuhiko, Akutagawa, Tomoyuki, Fukumura, Tomoteru, Yamashita, Masahiro |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8789904/ https://www.ncbi.nlm.nih.gov/pubmed/35078998 http://dx.doi.org/10.1038/s41467-022-28134-w |
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