Enhanced N-directed electrophilic C–H borylation generates BN–[5]- and [6]helicenes with improved photophysical properties

Helicenes are chiral polycyclic aromatic hydrocarbons (PAHs) of significant interest, e.g. in supramolecular chemistry, materials science and asymmetric catalysis. Herein an enhanced N-directed electrophilic C–H borylation methodology has been developed that provides access to azaborine containing h...

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Detalles Bibliográficos
Autores principales: Yuan, Kang, Volland, Daniel, Kirschner, Sven, Uzelac, Marina, Nichol, Gary S., Nowak-Król, Agnieszka, Ingleson, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8790800/
https://www.ncbi.nlm.nih.gov/pubmed/35211280
http://dx.doi.org/10.1039/d1sc06513k

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