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Competing C–H and C–F bond activation reactions of a fluorinated olefin at Rh: a fluorido vinylidene complex as an intermediate in an unprecedented dehydrofluorination step

The hydrofluoroolefin Z-1,3,3,3-tetrafluoropropene has been activated via an initial C–F bond activation and subsequent C–H bond activation using [Rh(H)(PEt(3))(3)] (1) or via C–H bond activation at [Rh(CH(3))(PEt(3))(3)] (8). In both cases the formation of [Rh{(E)-CF[double bond, length as m-dash]C...

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Detalles Bibliográficos
Autores principales:	Talavera, Maria, Braun, Thomas
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8790890/ https://www.ncbi.nlm.nih.gov/pubmed/35211279 http://dx.doi.org/10.1039/d1sc06713c

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