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Mechanistic differences between methanol and dimethyl ether in zeolite-catalyzed hydrocarbon synthesis

Water influences critically the kinetics of the autocatalytic conversion of methanol to hydrocarbons in acid zeolites. At very low conversions but otherwise typical reaction conditions, the initiation of the reaction is delayed in presence of H(2)O. In absence of hydrocarbons, the main reactions are...

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Detalles Bibliográficos
Autores principales:	Kirchberger, Felix M., Liu, Yue, Plessow, Philipp N., Tonigold, Markus, Studt, Felix, Sanchez-Sanchez, Maricruz, Lercher, Johannes A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	National Academy of Sciences 2022
Materias:	Physical Sciences
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8794837/ https://www.ncbi.nlm.nih.gov/pubmed/35046020 http://dx.doi.org/10.1073/pnas.2103840119

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